Herbicidal azobenzenesulfonamides

ABSTRACT

Azobenzenesulfonamides such as 2-[4-(dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide are useful as preemergent and postemergent herbicides.

BACKGROUND OF THE INVENTION

Benzenesulfonamides having a nitrogen-containing substituents on thebenzene ring are known as being herbicidal. For example, U.S. Pat. No.4,369,058 discloses herbicidal benzenesulfonamides of the generalformula ##STR1## where R₁ is H, Cl, Br, F, C₁ -C₄ alkyl, OCH₃ or NO₂ ;and

R₂ is NCO, NHCO₂ R₃, NHCOSR₃, NHCOR₃, NHCONR₄ R₅ or NR₆ R₇.

European Patent Application (EP-A) No. 102,924 discloses herbicidalazidobenzenesulfonamides of the formula ##STR2## where R₁ is H, halo,NO₂, C₁ -C₄ alkyl, C₁ -C₄ haloalkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy,C₁ -C₄ alkoxycarbonyl, C₁ -C₄ alkylthio, C₁ -C₄ alkylsulfinyl, C₁ -C₄alkylsulfonyl or C₂ -C₅ alkoxyalkoxy.

The present invention provides a novel class of benzenesulfonamides.

SUMMARY OF THE INVENTION

This invention pertains to novel compounds of Formulae I and II,agriculturally suitable compositions containing them and their method ofuse as general and/or selective, preemergent and postemergentherbicides. ##STR3## wherein R is H or CH₃ ;

R₁ is NR₄ R₅, N(CH₃)OR₆, NHCN, NRA, P(W)R₄ (W₁ R₅), P(W)(W₁ R₄)(W₂ R₅),P⁺ (C₆ H₅)₃, P⁺ R₆ R₇ R₈, SR₉, SO₂ R₉, C(R₁₀)(R₁₁)NO₂, CH(CN)₂ or Q;

Q is ##STR4## R₂ is H, F, Cl, Br, OCH₃, OC₂ H₅, OCF₂ H, SCH₃, N(CH₃)₂,NO₂, CH₃ or CF₃ ;

R₃ is H, F, Cl, Br, C₁ -C₄ alkyl, CO₂ R₁₅, NO₂, CF₃, C₁ -C₄ alkoxy, C₁-C₄ alkylthio, SO₂ NR₁₆ R₁₇, C₁ -C₄ alkylsulfonyl, C₁ -C₄ haloalkoxy, C₁-C₄ alkylsulfonyloxy, C₂ -C₅ alkoxyalkyl or C₃ -C₄ alkenyloxy;

R₄ and R₅ are independently C₁ -C₄ alkyl, C₂ -C₄ alkyl substituted by 1atom of Br or 1-3 atoms of F or Cl, C₃ -C₅ alkenyl, C₃ -C₅ cycloalkyl,OH, OCH₃, CH₂ OH, CH₂ OR₆, or CH₂ CH₂ OR₆ ; or

R₄ and R₅ may be taken together as --(CH₂)₄ --, --(CH₂)₅ -- or --(CH₂)₂O(CH₂)₂ --;

R₆ is C₁ -C₄ alkyl;

R₇ and R₈ are independently C₁ -C₄ alkyl;

R₉ is C₁ -C₄ alkyl, phenyl or phenyl substituted with 1-3 atoms of F, Clor 1 Br;

R₁₀ and R₁₁ are independently H, C₁ -C₄ alkyl, phenyl or phenylsubstituted with 1 atom of Br or 1-3 atoms of F or Cl;

R₁₂ is C₁ -C₄ alkyl, C₁ -C₄ alkoxy or NHR₉ ;

R₁₃ and R₁₄ are independently H, C₁ -C₃ alkyl, OR₆, SR₆, NHC(O)R₆, F,Cl, Br or CO₂ R₆ ;

R₁₅ is C₁ -C₄ alkyl, C₃ -C₄ alkenyl, CH₂ CH₂ Cl or CH₂ CH₂ OCH₃ ;

R₁₆ and R₁₇ are independently C₁ -C₂ alkyl;

W is O or S;

W₁ and W₂ are independently O, S or NH;

A is ##STR5## X is CH₃, OCH₃, OCH₂ CH₃, Cl, F, Br, I, OCF₂ H, CH₂ F,OCH₂ CH₂ F, OCH₂ CHF₂, OCH₂ CF₃ or CF₃ ;

Y is H, C₁ -C₃ alkyl, OCH₃, OC₂ H₅, CH₂ OCH₃, NHCH₃, N(OCH₃)CH₃,N(CH₃)₂, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, CH₂ OCH₂ CH₃, OCH₂ CH₂OCH₃, ##STR6## OCF₂ H, SCF₂ H or cyclopropyl; m is 2 or 3;

L₁ and L₂ are independently O or S;

R₁₈ is H or CH₃ ;

Z is CH or N;

Y₁ is O or CH₂ ;

X₁ is CH₃, OCH₃, OC₂ H₅ or OCF₂ H; and

Y₂ is H or CH₃ ;

provided that

(a) when X is Cl, F, Br or I, then Z is CH and Y is OCH₃, OC₂ H₅,N(OCH₃)CH₃, NHCH₃, N(CH₃)₂ or OCF₂ H;

(b) when either X or Y is OCF₂ H, then Z is CH; and

(c) when Q is Q-11 or Q-12, then R₁₃ is other than H;

and their agriculturally suitable salts.

Preferred for reason of increased ease of synthesis and/or greaterherbicidal efficacy are:

(1) Compounds of Formulae I or II where R is H and A is A-1;

(2) Compounds of Preferred 1 where X is CH₃, OCH₃ or Cl and Y is CH₃,OCH₃, OC₂ H₅ or CH₂ OCH₃ ; and

(3) Compounds of Preferred 2 where R₂ is H, Cl, CH₃ or OCH₃ and R₃ isCl, C₁ -C₃ alkyl, C₁ -C₃ alkoxy, NO₂, CO₂ (C₁ -C₃ alkyl), SO₂ N(CH₃)₂,OSO₂ CH₃, OSO₂ C₂ H₅, SO₂ CH₃, SO₂ C₂ H₅ or allyloxy.

Specifically preferred for reason of greatest ease of synthesis and/orgreatest herbicidal efficacy are:

2-[4-(dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide;

[[2-[[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]phenyl]azo]phosphonicacid, dimethylester; and

2-(dimethyl-1-triazeno)-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide.

DETAILED DESCRIPTION OF THE INVENTION Synthesis

Compounds of Formulae I and II can be prepared from the correspondingamino compounds of Formula III by diazotization and coupling with theappropriate reagent as illustrated in Equation 1. ##STR7## Diazotizationcan be carried out in a mixture of acetic and propionic acid to allowlower tempertures and aid in solution of the amine. Sodium nitrite andsufficient hydrochloric acid and water to promote rapid diazotizationare added and the mixture held at -10° to 25° C. for 30 minutes to 10hours.

Alternatively, the esters of nitrous acid, such as n-butylnitrite andamylnitrite may be used to effect diazotization in organic solvents suchas alcohols, acetic acid, dioxane and other media.

These and other methods of diazotization are extensively reviewed by H.Zollinger, "Azo and Diazo Chemistry, Aliphatic and Aromatic Compounds",Interscience Publishers, Inc., New York, N.Y. 1961, pp. 13-23 and S.Patai, Editor, "The Chemistry of Diazonium and Diazo Groups", Part II,John Wiley and Sons, New York, N.Y. 1978, pp. 645-659.

Compounds of Formulae I and II can also be prepared by reaction of theappropriate azobenzenesulfonamide (V) with the phenylcarbamate of theheterocyclic amine (VI) in the presence of one equivalent of1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as shown in Equation 2.##STR8##

The reaction of Equation 2 is preferably carried out by methodsanalogous to those described in European Patent Application (EP-A) No.85,028. The phenylcarbamates of Formula VI can be prepared by thereaction of an appropriate heterocyclic amine of Formula ANH₂ withdiphenylcarbonate or phenylchloroformate in the presence of a suitablebase by methods known to those skilled in the art.

Azobenzenesulfonamides of Formula V can be prepared from thecorresponding aminosulfonamides of Formula VII as shown below inEquation 3. ##STR9## Diazotization can be carried out as described forEquation 1 above.

The coupling of the diazonium salt intermediates IV or VIII with aprimary or secondary amine to produce a triazene where R₁ is NR₄ R₅,N(CH₃)OR₆, NHCN, NRA, ##STR10## is discussed in the two previousreferences, Zollinger, p. 177 and Patai, p. 247. The coupling to activemethylene compounds where R₁ is C(R₁₀)(R₁₁)NO₂, CH(CN)₂ or Q where Q isQ-1, Q-2, Q-3, Q-4, Q-5, Q-6 and Q-7 is discussed in Zollinger, p. 199and Patai, 268. Coupling with sulfur compounds where R₁ is SR₉, SO₂ R₉,and SO₂ OR₉ is discussed in Zollinger, p. 150 and Patai, p. 260.Coupling with phosphorous compounds where R₁ is P(W)R₄ (W₁ R₅), P(W)(W₁R₄)(W₂ R₅), P⁺ (Ph)₃, P⁺ R₆ R₇ R₈ is discussed in Zollinger, p. 152 andby F. Suckfull and H. Haubrich, Angew Chem. 70(8) 238 (1958). Couplingwith active aromatic ring systems where R₁ is Q-9, Q-10, Q-11, Q-12,Q-13 and Q-14 is well known in the art of dye preparation, as shown forexample in H. A. Lubs, Editor, "The Chemistry of Synthetic Dyes andPigments" Reinhold Publishing Corp., New York, 1955.

Methods suitable for the preparation of amino compounds of Formulae IIIand VII can be found in U.S. Pat. Nos. 4,225,337 and 4,369,058. Minormodifications of these methods, where appropriate, would be obvious toone skilled in the art.

The synthesis of heterocyclic amine derivatives has been reviewed in"The Chemistry of Heterocyclic Compounds," a series published byInterscience Publ., New York and London. 2-Aminopyrimidines aredescribed by D. J. Brown in "The Pyrimidines", Vol. XVI of the aboveseries. 2-Amino-1,3,5-triazines can be synthesized according to themethods described by E. M. Smolin and L. Rapaport in "s-Triazines andDerivatives," Vol. XIII of the same series. The synthesis of bicyclicpyrimidineamines is described in U.S. Pat. No. 4,339,267. Thepreparation of pyrimidines and triazines with acetal and ketalsubstituents is described in European Patent Application (EP-A) No.84,224 and cyclopropyl substituted systems are taught in EP-A No.108,708.

Agriculturally suitable salts of compounds of Formulae I or II are alsouseful herbicides and can be prepared in a number of ways known to theart. For example, metal salts can be made by contacting compounds ofFormulae I or II with a solution of an alkali or alkaline earth metalsalt having a sufficiently basic anion (e.g., hydroxide, alkoxide,carbonate or hydroxide). Quaternary amine salts can be made by similartechniques.

Salts of compounds of Formula I or II can also be prepared by exchangeof one cation for another. Cationic exchange can be effected by directcontact of an aqueous solution of a salt of a compound of Formulae I orII (e.g., alkali or quaternary amine salt) with a solution containingthe cation to be exchanged. This method is most effective when thedesired salt containing the exchanged cation is insoluble in water andcan be separated by filtration.

Exchange can also be effected by passing an aqueous solution of a saltof a compound of Formulae I or II (e.g., an alkali metal or quaternaryamine salt) through a column packed with a cation exchange resincontaining the cation to be exchanged for that of the original salt andthe desired product is eluted from the column. This method isparticularly useful when the desired salt is water-soluble.

Acid addition salts useful in this invention can be obtained by reactinga compound of Formulae I or II with a suitable acid, e.g.,p-toluenesulfonic acid, trichloroacetic acid or the like.

The synthesis of compounds described in this invention are furtherillustrated by the following Examples 1 through 3.

EXAMPLE 12-(Dimethyl-1-triazeno)-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide

2-Amino-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide(3.0 g) in acetic acid (30 mL), propionic acid (20 mL), water (10 mL)and concentrated HCl (2.0 mL) was cooled to 0° C. To this mixture wasadded sodium nitrite (0.75 g) with stirring. The mixture was held at-10° to 0° C. for 45 minutes. The mixture was then added to an ice andwater slurry containing dimethylamine (150 mL, 25% dimethylamine inwater). The homogeneous solution was acidified with acetic acid and theheavy white precipitate filtered, washed with water and dried in vacuo,to afford 2.94 g of the title compound as a white solid, m.p. 158°-160°C.

IR: 1705 cm⁻¹, 1620 cm⁻¹.

NMR (CDCl₃): δ 2.4 (s, 3), 3.3 (d, 6), 3.9 (s, 3), 6.3 (s, 1), 7.2-7.7(m, 3) and 8.3 (d, 1).

EXAMPLE 2[[2-[[(4-Methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]phenyl]azo]phosphoricacid, dimethyl ester

2-Amino-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide(2.0 g) in acetic acid (20 mL) and propionic acid (10 mL) was treatedwith concentrated hydrochloric acid (1.0 mL) at 0° C. A thickprecipitate formed immediately. Sodium nitrite was added (0.41 g) andthe slurry rapidly thinned and was stirred at -10° to 0° C. for 1 hour.To the homogeneous solution was added dimethylphosphite (1.0 mL) andenough sodium hydroxide to raise the pH to 7.0. After stirring for 30minutes, the mixture was diluted with water and extracted with ethylacetate, water washed, dried and evaporated to a red oil. Chromatographygave a pure fraction of 0.28 g of the title compound, m.p. 155°-156° C.

IR: 3300 cm⁻¹, 1710 cm⁻¹ ; 1700 cm⁻¹.

NMR (CDCl₃): δ 2.4 (s, 3), 3.9 (s, 3), 3.95 (d, 6), 6.25 (s, 1), 7.2 (m,1), 7.5 (m, 1), 7.8 (m, 1) and 8.45 (m, 1).

EXAMPLE 32-[(4-Dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide

2-Amino-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide(1.0 g) in acetic acid (25 mL) was treated with n-butyl nitrite (0.31 g)at 25° C. for 3 hours. The solution became homogeneous on addition ofthe n-butyl nitrite. N,N-Dimethylaniline (0.5 g) was then added and themixture stirred at 25° C. for 2 hours. The fine orange crystals werefiltered and water washed and dried to afford 0.47 g of the titlecompound, m.p. 210°-211° C. A second crop was isolated from thefiltrate, 0.2 g, m.p. 198°-204° C.

IR: 1710 cm⁻¹.

NMR (TFA): δ 2.6 (s, 3), 3.6 (s, 6), 4.2 (s, 3), 6.6 (s, 1) and 7.2-8.2(m, 8).

Using the procedures of Examples 1-3, and the synthetic routes disclosedherein, the compounds of Tables I-XXXII can be prepared.

    ______________________________________                                        GENERAL FORMULAS FOR TABLES I- XXXII                                          ______________________________________                                               ##STR11##                                                              II                                                                                   ##STR12##                                                              III                                                                                  ##STR13##                                                              IV                                                                                   ##STR14##                                                              V                                                                                    ##STR15##                                                              VI                                                                                   ##STR16##                                                              VII                                                                                  ##STR17##                                                              VIII                                                                                 ##STR18##                                                              IX                                                                                   ##STR19##                                                              X                                                                                    ##STR20##                                                              XI                                                                                   ##STR21##                                                              XII                                                                                  ##STR22##                                                              XIII                                                                                 ##STR23##                                                              XIV                                                                                  ##STR24##                                                              XV                                                                                   ##STR25##                                                              XVI                                                                                  ##STR26##                                                              XVII                                                                                 ##STR27##                                                              XVIII                                                                                ##STR28##                                                              XIX                                                                                  ##STR29##                                                              XX                                                                                  ##STR30##                                                               XXI                                                                                  ##STR31##                                                              XXII                                                                                 ##STR32##                                                              XXIII                                                                                ##STR33##                                                              XXIV                                                                                 ##STR34##                                                              XXV                                                                                  ##STR35##                                                              XXVI                                                                                 ##STR36##                                                              XXVII                                                                                ##STR37##                                                              XXVIII                                                                                ##STR38##                                                             XXIX                                                                                 ##STR39##                                                              XXX                                                                                  ##STR40##                                                              XXXI                                                                                 ##STR41##                                                              XXXII                                                                                ##STR42##                                                              ______________________________________                                    

                                      TABLE I                                     __________________________________________________________________________    General Formula I                                                             R  R.sub.1        R.sub.2                                                                             X      Y          Z  m.p. (°C.)                __________________________________________________________________________    H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             CH.sub.3   CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             OCH.sub.3  CH 158-160                          H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             CH.sub.3   N                                   H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             OCH.sub.3  N                                   H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                            OCH.sub.3  N                                   CH.sub.3                                                                         N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            6-F   OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            6-Cl  OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            6-Br  OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            5-OCH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            5-F   OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            3-OC.sub.2 H.sub.5                                                                  OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            6-OCF.sub.2 H                                                                       OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub. 3).sub.2                                                                           5-SCH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            5-N(CH.sub.3).sub.2                                                                 OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            5-NO.sub.2                                                                          OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            6-CH.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            6-CF.sub.3                                                                          OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(C.sub.2 H.sub.5).sub.2                                                                     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3)C.sub.4 H.sub.9                                                                   H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3)CH.sub.2 CF.sub.3                                                                 H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.2 CH.sub.2 Cl).sub.2                                                                H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3)CH.sub.2 CH.sub.2 Br                                                              H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3)CH.sub.2 CHCH.sub.2                                                               H     OCH.sub.3                                                                            OCH.sub.3  CH                                      ##STR43##     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(OH)CH.sub.3  H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(OCH.sub.3)CH.sub.3                                                                         H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3)CH.sub.2 OH                                                                       H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3)CH.sub.2 OCH.sub. 3                                                               H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3)(cyclopropyl)                                                                     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3)(cyclopentyl)                                                                     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H                                                                                 ##STR44##     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H                                                                                 ##STR45##     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H                                                                                 ##STR46##     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                       H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.3).sub.2                                                H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3)OC.sub.4 H.sub.9                                                                  H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  NHCN           H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H                                                                                 ##STR47##     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P(O)(OCH.sub.3).sub.2                                                                        H     CH.sub.3                                                                             OCH.sub.3  CH 155-156                          H  P(O)(CH.sub.3)OCH.sub.3                                                                      H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P(O)(CH.sub.2 CF.sub.3)OCH.sub.3                                                             H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P(O)(OCH.sub.3)CH.sub.2 CHCH.sub.2                                                           H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P(S)(CH.sub.3)OCH.sub.3                                                                      H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P(O)(CH.sub.3)SCH.sub.3                                                                      H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P(O)(CH.sub.3)NHCH.sub.3                                                                     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H                                                                                 ##STR48##     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P(O)(OCH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                   H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P(O)(OCH.sub.3)cyclopropyl                                                                   H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P.sup.+ ( -n-C.sub.4 H.sub.9).sub.3                                                          H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  P.sup.+ (CH.sub.3)(C.sub.2 H.sub.5).sub.2                                                    H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  SCH.sub.3      H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  Sn-C.sub.4 H.sub.9                                                                           H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  SC.sub.6 H.sub.5                                                                             H     OCH.sub. 3                                                                           OCH.sub.3  CH                                  H  S(3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                              H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  S(4-C.sub.6 H.sub.4 Cl)                                                                      H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  S(2-C.sub.6 H.sub.4 Br)                                                                      H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  SO.sub.2 CH.sub.3                                                                            H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  SO.sub.2 -n-C.sub.4 H.sub.9                                                                  H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  SO.sub.2 C.sub.6 H.sub.5                                                                     H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  SO.sub.2 (3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                      H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  SO.sub.2 (4-C.sub.6 H.sub.4 Cl)                                                              H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  SO.sub.2 (2-C.sub.6 H.sub.4 Br)                                                              H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  CH.sub.2 NO.sub.2                                                                            H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  CH(CH.sub.3)NO.sub.2                                                                         H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  C(CH.sub.3).sub.2 NO.sub.2                                                                   H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  C(CH.sub.3)(C.sub.6 H.sub.5)NO.sub.2                                                         H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  CH(C.sub.4 H.sub.9)NO.sub.2                                                                  H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  CH(4-C.sub.6 H.sub.4 Cl)NO.sub.2                                                             H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  CH(CN).sub.2   H     OCH.sub.3                                                                            OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            H     OC.sub.2 H.sub.5                                                                     CH.sub.3   N                                   H  N(CH.sub.3).sub.2                                                                            H     Cl     OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            H     F      OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            H     Br     OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            H     OCF.sub.2 H                                                                          CH.sub.3   CH                                  H  N(CH.sub.3).sub.2                                                                            H     CF.sub.2 H                                                                           CH.sub.3   CH                                  H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.2 CH.sub.2 F                                                                 CH.sub.3   CH                                  H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.2 CHF.sub.2                                                                  CH.sub.3   CH                                  H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.2 CF.sub.3                                                                   CH.sub.3   CH                                  H  N(CH.sub.3).sub.2                                                                            H     CF.sub.3                                                                             OCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                            H          CH                                  H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                       CH                                  H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                            NHCH.sub.3 N                                   H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                            N(OCH.sub.3)CH.sub.3                                                                     N                                   H  N(CH.sub.3).sub.2                                                                            H     OCH.sub.3                                                                            N(CH.sub.3).sub.2                                                                        N                                   H  N(CH.sub.3).sub.2                                                                            H     OCH.sub. 3                                                                           CH.sub.2 CH.sub.3                                                                        CH                                  H  N(CH.sub.3).sub.2                                                                            H     CF.sub.3                                                                             CF.sub.3   CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             SCH.sub.3  CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             OCH.sub.2 CCH                                                                            CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             OCH.sub.2 CHCH.sub.2                                                                     CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             CH.sub.2 OCH.sub.2 CH.sub.3                                                              CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             OCH.sub.2 CH.sub.2 OCH.sub.3                                                             CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             CH.sub.2 SCH.sub.3                                                                       CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             CHO        CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             COCH.sub.3 CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             CH(OCH.sub.3).sub.2                                                                      CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                              ##STR49## CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             OCF.sub.2 H                                                                              CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                                                             SCF.sub.2 H                                                                              CH                                  H  N(CH.sub.3).sub.2                                                                            H     CH.sub.3                                              cyclopropyl                                                                      CH                                                                         __________________________________________________________________________

                                      TABLE II                                    __________________________________________________________________________    General Formula II                                                            Q  R R.sub.2                                                                         R.sub.4                                                                              R.sub.5 R.sub.6                                                                           R.sub.9                                                                              R.sub.12                                                                            R.sub.13                                                                             R.sub.14                                                                             X   m.p.(°C.)     __________________________________________________________________________    Q-1                                                                              H H --     --      --  --     NHC.sub.6 H.sub.5                                                                   --     --     OCH.sub.3                Q-1                                                                              H H --     --      --  --     CH.sub.3                                                                            --     --     OCH.sub.3                Q-1                                                                              H H --     --      --  --     OCH.sub.3                                                                           --     --     OCH.sub.3                Q-1                                                                              H H --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --     OCH.sub.3                Q-1                                                                              H H --     --      --  --     NHCH.sub.3                                                                          --     --     OCH.sub.3                Q-2                                                                              H H --     --      --  CH.sub.3                                                                             CH.sub.3                                                                            --     --     OCH.sub.3                Q-2                                                                              H H --     --      --  C.sub.6 H.sub.5                                                                      CH.sub.3                                                                            --     --     OCH.sub.3                Q-2                                                                              H H --     --      --  CH.sub.3                                                                             OCH.sub.3                                                                           --     --     OCH.sub.3                Q-2                                                                              H H --     --      --  CH.sub.3                                                                             NHCH.sub.3                                                                          --     --     OCH.sub.3                Q-2                                                                              H H --     --      --  CH.sub.3                                                                             NHC.sub.6 H.sub.5                                                                   --     --     OCH.sub.3                Q-3                                                                              H H --     --      --  --     CH.sub.3                                                                            --     --     OCH.sub.3                Q-3                                                                              H H --     --      --  --     OCH.sub.3                                                                           --     --     OCH.sub.3                Q-3                                                                              H H --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --     OCH.sub.3                Q-3                                                                              H H --     --      --  --     NHCH.sub.3                                                                          --     --     OCH.sub.3                Q-4                                                                              H H --     --      --  --     CH.sub.3                                                                            --     --     OCH.sub.3                Q-4                                                                              H H --     --      --  --     OCH.sub.3                                                                           --     --     OCH.sub.3                Q-4                                                                              H H --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --     OCH.sub.3                Q-4                                                                              H H --     --      --  --     NHCH.sub.3                                                                          --     --     OCH.sub.3                Q-5                                                                              H H --     --      --  --     --    --     --     OCH.sub.3                Q-6                                                                              H H --     --      --  --     --    --     --     OCH.sub.3                Q-7                                                                              H H --     --      --  --     --    --     --     OCH.sub.3                Q-8                                                                              H H --     --      --  --     --    H      H      OCH.sub.3                Q-8                                                                              H H --     --      --  --     --    H      4-CH.sub.3                                                                           OCH.sub.3                Q-8                                                                              H H --     --      --  --     --    H      4-OCH.sub.3                                                                          OCH.sub.3                Q-8                                                                              H H --     --      --  --     --    H      3-SCH.sub.3                                                                          OCH.sub.3                Q-8                                                                              H H --     --      --  --     --    3-Cl   4-Cl   OCH.sub.3                Q-8                                                                              H H --     --      --  --     --    H      4-CO.sub.2 CH.sub.3                                                                  OCH.sub.3                Q-8                                                                              H H --     --      --  --     --    2-OCH.sub.3                                                                          5-OCH.sub.3                                                                          OCH.sub.3                Q-8                                                                              H H --     --      --  --     --    2-F    5-NHCOCH.sub.3                                                                       OCH.sub.3                Q-9                                                                              H H CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    H      H      CH.sub.3                                                                          210-211              Q-9                                                                              H H CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-NHCOCH.sub.3                                                                       H      OCH.sub.3                Q-9                                                                              H H CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-Cl   H      OCH.sub.3                Q-9                                                                              H H CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-OCH.sub.3                                                                          H      OCH.sub.3                Q-9                                                                              H H CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-SCH.sub.3                                                                          H      OCH.sub.3                Q-9                                                                              H H C.sub.2 H.sub.5                                                                      C.sub.2 H.sub.5                                                                       --  --     --    H      H      OCH.sub.3                Q-9                                                                              H H CH.sub.3                                                                             CH.sub.2 CH═CH.sub.2                                                              --  --     --    H      H      OCH.sub.3                Q-9                                                                              H H CH.sub.2 CH.sub.2 Cl                                                                 CH.sub.2 CH.sub.2 Cl                                                                  --  --     --    H      H      OCH.sub.3                Q-9                                                                              H H CH.sub.2 CH.sub.2 OH                                                                 CH.sub.2 CH.sub.2 OH                                                                  --  --     --    H      H      OCH.sub.3                Q-9                                                                              H H --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                    --  --     --    H      H      OCH.sub.3                Q-10                                                                             H H --     --      --  --     --    H      H      OCH.sub.3                Q-10                                                                             H H --     --      --  --     --    2-NHCOCH.sub.3                                                                       H      OCH.sub.3                Q-10                                                                             H H --     --      --  --     --    2-Cl   H      OCH.sub.3                Q-10                                                                             H H --     --      --  --     --    2-OCH.sub.3                                                                          H      OCH.sub.3                Q-10                                                                             H H --     --      --  --     --    2-SCH.sub.3                                                                          H      OCH.sub.3                Q-10                                                                             H H --     --      --  --     --    3-CO.sub.2 CH.sub.3                                                                  H      OCH.sub.3                Q-10                                                                             H H --     --      --  --     --    3-Cl   5-Cl   OCH.sub.3                Q-11                                                                             H H CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    H      H      OCH.sub.3                Q-11                                                                             H H CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-NHCOCH.sub.3                                                                       H      OCH.sub.3                Q-11                                                                             H H CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-Cl   H      OCH.sub.3                Q-11                                                                             H H CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-OCH.sub.3                                                                          H      OCH.sub.3                Q-11                                                                             H H CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-SCH.sub.3                                                                          H      OCH.sub.3                Q-11                                                                             H H C.sub.2 H.sub.5                                                                      C.sub.2 H.sub.5                                                                       --  --     --    H      H      OCH.sub.3                Q-11                                                                             H H CH.sub.3                                                                             CH.sub.2 CH═CH.sub.2                                                              --  --     --    H      H      OCH.sub.3                Q-11                                                                             H H CH.sub.2 CH.sub.2 Cl                                                                 CH.sub.2 CH.sub.2 Cl                                                                  --  --     --    H      H      OCH.sub.3                Q-11                                                                             H H CH.sub.2 CH.sub.2 OH                                                                 CH.sub.2 CH.sub.2 OH                                                                  --  --     --    H      H      OCH.sub.3                Q-11                                                                             H H --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                    --  --     --    H      H      OCH.sub.3                Q-12                                                                             H H --     --      --  --     --    H      H      OCH.sub.3                Q-12                                                                             H H --     --      --  --     --    4-NHCOCH.sub.3                                                                       H      OCH.sub.3                Q-12                                                                             H H --     --      --  --     --    4-Cl   H      OCH.sub.3                Q-12                                                                             H H --     --      --  --     --    4-OCH.sub.3                                                                          H      OCH.sub.3                Q-12                                                                             H H --     --      --  --     --    4-SCH.sub.3                                                                          H      OCH.sub.3                Q-12                                                                             H H --     --      --  --     --    4-CO.sub.2 CH.sub.3                                                                  H      OCH.sub.3                Q-12                                                                             H H --     --      --  --     --    3-Cl   5-Cl   OCH.sub.3                Q-13                                                                             H H --     --      CH.sub.3                                                                          H      --    --     --     OCH.sub.3                Q-13                                                                             H H --     --      C.sub.4 H.sub.9                                                                   CH.sub.3                                                                             --    --     --     OCH.sub.3                Q-13                                                                             H H --     --      CH.sub.3                                                                          C.sub.6 H.sub.5                                                                      --    --     --     OCH.sub.3                Q-13                                                                             H H --     --      CH.sub.3                                                                          4-C.sub.6 H.sub.4 Cl                                                                 --    --     --     OCH.sub.3                Q-13                                                                             H H --     --      CH.sub.3                                                                          2,4-C.sub.6 H.sub.3 Cl.sub.2                                                         --    --     --     OCH.sub.3                Q-13                                                                             H H --     --      CH.sub.3                                                                          CH.sub.3                                                                             --    --     --     OCH.sub.3                Q-14                                                                             H H --     --      --  CH.sub.3                                                                             --    H      --     OCH.sub.3                Q-14                                                                             H H --     --      --  C.sub.6 H.sub.5                                                                      --    H      --     OCH.sub.3                Q-14                                                                             H H --     --      --  4-C.sub.6 H.sub.4 Cl                                                                 --    H      --     OCH.sub.3                Q-14                                                                             H H --     --      --  CH.sub.3                                                                             --    CH.sub.3                                                                             --     OCH.sub.3                Q-14                                                                             H H --     --      --  CH.sub.3                                                                             --    Cl     --     OCH.sub.3                Q-14                                                                             H H --     --      --  CH.sub.3                                                                             --    OCH.sub.3                                                                            --     OCH.sub.3                __________________________________________________________________________

                                      TABLE III                                   __________________________________________________________________________    General Formula III                                                           R  R.sub.1        R.sub.3     X      Y          Z  m.p.                       __________________________________________________________________________                                                       (°C.)               CH.sub.3                                                                         N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            NO.sub.2    CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                            CH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                            NO.sub.2    OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            CF.sub.3    CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CF.sub. 3   OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CF.sub.3    CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            CF.sub.3    OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            OCH.sub.3   OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            SCH.sub.3   OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                         CH.sub. 3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 Cl                                                                     OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 Cl                                                                     CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH CH.sub.2                                                                     CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                      OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                      CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CHCH.sub.2                                                                      OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            CH.sub.3    CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CH.sub.3    OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CH.sub.3    CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            CH.sub.3    OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            Cl          CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            Cl          OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            Cl          CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            Cl          OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            Br          CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            Br          OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            Br          CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            Br          OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            F           CH.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            F           OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            F           CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            F           OCH.sub.3                                                                            OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                            H           OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            H           CH.sub.3                                                                             OCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                             -n-C.sub.4 H.sub.9                                                                       OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.3                                                                OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 .sub.-i-C.sub.3 H.sub.7                                                          OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2CH.sub.2 CHCH.sub.2                                                               OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.2 Cl                                                             OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.2 CH.sub.2 OCH.sub.3                                                      OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            OC.sub.4 H.sub.9                                                                          OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            SC.sub.4 H.sub.9                                                                          OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub. 2                                                                           SO.sub.2 N(C.sub.2 H.sub.5).sub.2                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.2 CH.sub.3                                                                OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            SO.sub.2 C.sub.4 H.sub.9                                                                  OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 Br                                                   OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            OSO.sub.2 C.sub.4 H.sub.9                                                                 OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(C.sub.2 H.sub.5).sub.2                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3)CH.sub.2 CF.sub.3                                                                 CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.2 CH.sub.2 Cl).sub.2                                                                CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3)CH.sub.2 CH.sub.2 Br                                                              CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3)CH.sub.2 CHCH.sub.2                                                               CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                                ##STR50##     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub. 3 CH                            H  N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(OCH.sub.3)CH.sub.3                                                                         CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3)CH.sub.2 OCH.sub.3                                                                CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3)(cyclopropyl)                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3)(cyclopentyl)                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H                                                                                 ##STR51##     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H                                                                                 ##STR52##     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H                                                                                 ##STR53##     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                       CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.3).sub.2                                                CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub. 3)OC.sub.4 H.sub.9                                                                 CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  NHCN           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H                                                                                 ##STR54##     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.3  CH                            H  P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P(O)(CH.sub.2 CF.sub.3)OCH.sub.3                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P(O)(OCH.sub.3)CH.sub.2 CHCH.sub.2                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P(O)(CH.sub.3)SCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P(O)(CH.sub.3)NHCH.sub.3                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H                                                                                 ##STR55##     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P(O)(OCH.sub.3 )CH.sub.2 CH.sub.2 OCH.sub.3                                                  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P(O)(OCH.sub.3)cyclopropyl                                                                   CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P.sup.+ ( -n-C.sub.4 H.sub.9).sub.3                                                          CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  P.sup.+ (CH.sub.3)(C.sub.2 H.sub.5).sub.2                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  SCH.sub.3      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  S -n-C.sub.4 H.sub.9                                                                         CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  SC.sub.6 H.sub.5                                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  S(3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                              CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  S(4-C.sub.6 H.sub.4 Cl)                                                                      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  S(2-C.sub.6 H.sub.4 Br)                                                                      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  SO.sub.2  -n-C.sub.4 H.sub.9                                                                 CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  SO.sub.2 C.sub.6 H.sub.5                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  SO.sub.2 (3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  SO.sub.2 (4-C.sub.6 H.sub.4 Cl)                                                              CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  SO.sub.2 (2-C.sub.6 H.sub.4 Br)                                                              CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  CH(CH.sub.3)NO.sub.2                                                                         CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  C(CH.sub.3).sub.2 NO.sub.2                                                                   CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  C(CH.sub.3)(C.sub.6 H.sub.5)NO.sub.2                                                         CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  CH(C.sub.4 H.sub.9)NO.sub.2                                                                  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  CH(4-C.sub.6 H.sub.4 Cl)NO.sub.2                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub. 2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OC.sub.2 H.sub.5                                                                     CH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         Cl     OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         F      OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         Br     OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCF.sub.2 H                                                                          CH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CF.sub.2 H                                                                           CH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.2 CH.sub.2 F                                                                 CH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.2 CHF.sub.2                                                                  CH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.2 CF.sub.3                                                                   CH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CF.sub.3                                                                             OCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            H          CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                       CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            NHCH.sub.3 N                             H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            N(CH.sub.3)OCH.sub.3                                                                     N                             H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            N(CH.sub.3).sub.2                                                                        N                             H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.2 CH.sub.3                                                                        CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CF.sub.3                                                                             CF.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             SCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.2 CCH                                                                            CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.2 CHCH.sub.2                                                                     CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH.sub.2 OCH.sub.2 CH.sub.3                                                              CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 OCH.sub.3                                                             CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.2 SCH.sub.3                                                                       CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CHO        CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             COCH.sub.3 CH                            H  N(CH.sub. 3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH(OCH.sub.3).sub.2                                                                      CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                              ##STR56## CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCF.sub.2 H                                                                              CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             SCF.sub.2 H                                                                              CH                            H  N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                         CH.sub.3                                        cyclopropyl                                                                      CH                                                                         __________________________________________________________________________

                                      TABLE IV                                    __________________________________________________________________________    General Formula IV                                                                                                                     m.p.                 Q  R  R.sub.2                                                                            R.sub.4                                                                              R.sub.5 R.sub.6                                                                           R.sub.9                                                                              R.sub.12                                                                            R.sub.13                                                                             R.sub.14                                                                             (°C.)         __________________________________________________________________________    Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHC.sub.6 H.sub.5                                                                   --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     CH.sub.3                                                                            --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     OCH.sub.3                                                                           --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHCH.sub.3                                                                          --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             CH.sub.3                                                                            --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  C.sub.6 H.sub.5                                                                      CH.sub.3                                                                            --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             OCH.sub.3                                                                           --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             NHCH.sub.3                                                                          --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             NHC.sub.6 H.sub.5                                                                   --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     CH.sub.3                                                                            --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     OCH.sub.3                                                                           --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHCH.sub.3                                                                          --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     CH.sub.3                                                                            --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     OCH.sub. 3                                                                          --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHCH.sub.3                                                                          --     --                          Q-5                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    --     --                          Q-6                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    --     --                          Q-7                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    --     --                          Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      H                           Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      4-CH.sub.3                  Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      4-OCH.sub.3                 Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      3-SCH.sub.3                 Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-Cl   4-Cl                        Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      4-CO.sub.2 CH.sub.3         Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-OCH.sub.3                                                                          5-OCH.sub.3                 Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-F    5-NHCOCH.sub.3              Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    H      H      221-231              Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-NHCOCH.sub.3                                                                       H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-Cl   H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-OCH.sub.3                                                                          H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-SCH.sub.3                                                                          H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  C.sub.2 H.sub.5                                                                      C.sub.2 H.sub.5                                                                       --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.2 CH═CH.sub.2                                                              --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 Cl                                                                 CH.sub.2 CH.sub.2 Cl                                                                  --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 OH                                                                 CH.sub.2 CH.sub.2 OH                                                                  --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                    --  --     --    H      H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-NHCOCH.sub.3                                                                       H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-Cl   H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-OCH.sub.3                                                                          H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-SCH.sub.3                                                                          H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-CO.sub.2 CH.sub.3                                                                  H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-Cl   5-Cl                        Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-NHCOCH.sub.3                                                                       H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-Cl   H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-OCH.sub.3                                                                          H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-SCH.sub.3                                                                          H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  C.sub.2 H.sub.5                                                                      C.sub.2 H.sub.5                                                                       --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.2 CH═CH.sub.2                                                              --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 Cl                                                                 CH.sub.2 CH.sub.2 Cl                                                                  --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 OH                                                                 CH.sub. 2 CH.sub.2 OH                                                                 --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                    --  --     --    H      H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-NHCOCH.sub.3                                                                       H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-Cl   H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-OCH.sub.3                                                                          H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-SCH.sub.3                                                                          H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-CO.sub.2 CH.sub.3                                                                  H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-Cl   5-Cl                        Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          H      --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      C.sub.4 H.sub.9                                                                   CH.sub.3                                                                             --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          C.sub.6 H.sub.5                                                                      --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          4-C.sub.6 H.sub.4 Cl                                                                 --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          2,4-C.sub.6 H.sub.3 Cl.sub.2                                                         --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          CH.sub.3                                                                             --    --     --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    H      --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  C.sub.6 H.sub.5                                                                      --    H      --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  4-C.sub.6 H.sub.4 Cl                                                                 --    H      --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    CH.sub.3                                                                             --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    Cl     --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    OCH.sub.3                                                                            --                          __________________________________________________________________________

                                      TABLE V                                     __________________________________________________________________________    General Formula V                                                             R  R.sub.1       R.sub.3     X      Y           Z  m.p.                       __________________________________________________________________________                                                       (°C.)               CH.sub.3                                                                         N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH.sub.3    N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.3    N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           NO.sub.2    CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           NO.sub.2    OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           NO.sub.2    OCH.sub.3                                                                            CH.sub.3    N                             H  N(CH.sub.3).sub.2                                                                           NO.sub.2    OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CF.sub.3    CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CF.sub.3    OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CF.sub.3    CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CF.sub.3    OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OCH.sub.3   CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.3   OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.3   CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OCH.sub.3   OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SCH.sub.3   CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SCH.sub.3   OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SCH.sub.3   CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SCH.sub.3   OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SO.sub.2 N(CH.sub.3).sub.2                                                                CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 N(CH.sub.3).sub.2                                                                OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 N(CH.sub.3).sub.2                                                                CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SO.sub.2 N(CH.sub.3).sub.2                                                                OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CH.sub.2 Cl                                                                     OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CH.sub.2 Cl                                                                     CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OSO.sub.2 CH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OSO.sub.2 CH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OSO.sub.2 CH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OSO.sub.2 CH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CH.sub.2 OCH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CH.sub.2 OCH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CH.sub.2 OCH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CH.sub.2 OCH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CHCH.sub. 2                                                                     CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CHCH.sub.2                                                                      OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CHCH.sub.2                                                                      CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CHCH.sub.2                                                                      OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CH.sub.3    CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CH.sub.3    OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CH.sub.3    CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CH.sub.3    OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           Cl          CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           Cl          OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           Cl          CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           Cl          OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           Br          CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           Br          OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           Br          CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           Br          OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           F           CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub. 3).sub.2                                                                          F           OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           F           CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           F           OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           H           OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           H           CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                            -n-C.sub.4 H.sub.9                                                                       OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.2 CH.sub.3                                                                OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 .sub.-i-C.sub.3 H.sub.7                                                          OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2CH.sub.2 CHCH.sub.2                                                               OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.2 CH.sub.2 Cl                                                             OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.2 CH.sub.2 OCH.sub.3                                                      OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OC.sub.4 H.sub.9                                                                          OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SC.sub.4 H.sub.9                                                                          OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 N(C.sub.2 H.sub.5).sub.2                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 CH.sub.2 CH.sub.3                                                                OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 C.sub.4 H.sub.9                                                                  OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 Br                                                   OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OSO.sub.2 C.sub.4 H.sub.9                                                                 OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(C.sub.2 H.sub.5).sub.2                                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)C.sub.4 H.sub.9                                                                  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 CF.sub.3                                                                CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.2 CH.sub.2 Cl).sub.2                                                               CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 CH.sub.2 Br                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 CHCH.sub.2                                                              CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                                ##STR57##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub. 3  CH                            H  N(OH)CH.sub.3 CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(OCH.sub.3)CH.sub.3                                                                        CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 OH                                                                      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 OCH.sub.3                                                               CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)(cyclopropyl)                                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)(cyclopentyl)                                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H                                                                                 ##STR58##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H                                                                                 ##STR59##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H                                                                                 ##STR60##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.3).sub.2                                               CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3 )OC.sub.4 H.sub.9                                                                CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  NHCN          CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H                                                                                 ##STR61##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(OCH.sub.3).sub.2                                                                       CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.3   CH                            H  P(O)(CH.sub.3)OCH.sub.3                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(CH.sub.2 CF.sub.3)OCH.sub.3                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(OCH.sub.3)CH.sub.2 CHCH.sub.2                                                          CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(S)(CH.sub.3)OCH.sub.3                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(CH.sub.3)SCH.sub.3                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(CH.sub.3)NHCH.sub.3                                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H                                                                                 ##STR62##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(OCH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(OCH.sub.3)cyclopropyl                                                                  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P.sup.+ (C.sub.6 H.sub.5).sub.3                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P.sup.+ ( -n-C.sub.4 H.sub.9).sub.3                                                         CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P.sup.+ (CH.sub.3)(C.sub.2 H.sub.5).sub.2                                                   CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SCH.sub.3     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  S -n-C.sub.4 H.sub.9                                                                        CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SC.sub.6 H.sub.5                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  S(3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  S(4-C.sub.6 H.sub.4 Cl)                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  S(2-C.sub.6 H.sub.4 Br)                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 CH.sub.3                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 -n-C.sub.4 H.sub.9                                                                 CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 C.sub.6 H.sub.5                                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 (3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 (4-C.sub.6 H.sub.4 Cl)                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 (2-C.sub.6 H.sub.4 Br)                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  CH.sub.2 NO.sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  CH(CH.sub.3)NO.sub.2                                                                        CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  C(CH.sub.3).sub.2 NO.sub.2                                                                  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  C(CH.sub.3)(C.sub.6 H.sub.5)NO.sub.2                                                        CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  CH(C.sub.4 H.sub.9)NO.sub.2                                                                 CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  CH(4-C.sub.6 H.sub.4 Cl)NO.sub.2                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  CH(CN).sub.2  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub. 2 CH.sub.3                                                                        OC.sub.2 H.sub.5                                                                     CH.sub.3    N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         Cl     OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         F      OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         Br     OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCF.sub.2 H                                                                          CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CF.sub.2 H                                                                           CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.2 CH.sub.2 F                                                                 CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.2 CHF.sub.2                                                                  CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.2 CF.sub.3                                                                   CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CF.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            H           CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                        CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            NHCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            N(CH.sub.3)OCH.sub.3                                                                      N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            N(CH.sub.3).sub.2                                                                         N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.2 CH.sub.3                                                                         CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CF.sub.3                                                                             CF.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             SCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.2 CCH                                                                             CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.2 CHCH.sub.2                                                                      CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH.sub.2 OCH.sub.2 CH.sub.3                                                               CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 OCH.sub.3                                                              CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.2 SCH.sub.3                                                                        CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CHO         CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             COCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH(OCH.sub.3).sub.2                                                                       CH                            H  N(CH.sub. 3).sub.2                                                                          CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                              ##STR63##  CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCF.sub.2 H CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             SCF.sub.2 H CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             cyclopropyl CH                            __________________________________________________________________________

                                      TABLE VI                                    __________________________________________________________________________    General Formula VI                                                                                                                     m.p.                 Q  R  R.sub.2                                                                            R.sub.4                                                                              R.sub.5 R.sub.6                                                                           R.sub.9                                                                              R.sub.12                                                                            R.sub.13                                                                             R.sub.14                                                                             (°C.)         __________________________________________________________________________    Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHC.sub.6 H.sub.5                                                                   --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     CH.sub.3                                                                            --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     OCH.sub.3                                                                           --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHCH.sub.3                                                                          --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             CH.sub.3                                                                            --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  C.sub.6 H.sub.5                                                                      CH.sub.3                                                                            --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             OCH.sub.3                                                                           --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             NHCH.sub.3                                                                          --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             NHC.sub.6 H.sub.5                                                                   --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     CH.sub.3                                                                            --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     OCH.sub.3                                                                           --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHCH.sub.3                                                                          --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     CH.sub.3                                                                            --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     OCH.sub. 3                                                                          --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHCH.sub.3                                                                          --     --                          Q-5                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    --     --                          Q-6                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    --     --                          Q-7                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    --     --                          Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      H                           Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      4-CH.sub.3                  Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      4-OCH.sub.3                 Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      3-SCH.sub.3                 Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-Cl   4-Cl                        Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      4-CO.sub.2 CH.sub.3         Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-OCH.sub.3                                                                          5-OCH.sub.3                 Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-F    5-NHCOCH.sub.3              Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    H      H      221-231              Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-NHCOCH.sub.3                                                                       H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-Cl   H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-OCH.sub.3                                                                          H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-SCH.sub.3                                                                          H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  C.sub.2 H.sub.5                                                                      C.sub.2 H.sub.5                                                                       --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.2 CH═CH.sub.2                                                              --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 Cl                                                                 CH.sub.2 CH.sub.2 Cl                                                                  --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 Cl                                                                 CH.sub.2 CH.sub.2 OH                                                                  --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                    --  --     --    H      H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-NHCOCH.sub.3                                                                       H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-Cl   H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-OCH.sub.3                                                                          H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-SCH.sub.3                                                                          H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-CO.sub.2 CH.sub.3                                                                  H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-Cl   5-Cl                        Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-NHCOCH.sub.3                                                                       H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-Cl   H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-OCH.sub.3                                                                          H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-SCH.sub.3                                                                          H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  C.sub.2 H.sub.5                                                                      C.sub.2 H.sub.5                                                                       --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.2 CH═CH.sub.2                                                              --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 Cl                                                                 CH.sub.2 CH.sub.2 Cl                                                                  --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 OH                                                                 CH.sub. 2 CH.sub.2 OH                                                                 --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                    --  --     --    H      H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-NHCOCH.sub.3                                                                       H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-Cl   H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-OCH.sub.3                                                                          H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-SCH.sub.3                                                                          H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-CO.sub.2 CH.sub.3                                                                  H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-Cl   5-Cl                        Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          H      --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      C.sub.4 H.sub.9                                                                   CH.sub.3                                                                             --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          C.sub.6 H.sub.5                                                                      --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          2,4-C.sub.6 H.sub.4 Cl                                                               --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          2,4-C.sub.6 H.sub.3 Cl.sub.2                                                         --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          CH.sub.3                                                                             --    --     --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    H      --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  C.sub.6 H.sub.5                                                                      --    H      --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  4-C.sub.6 H.sub.4 Cl                                                                 --    H      --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    CH.sub.3                                                                             --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    Cl     --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    OCH.sub.3                                                                            --                          __________________________________________________________________________

                                      TABLE VII                                   __________________________________________________________________________    General Formula VII                                                           R  R.sub.1       R.sub.3     X      Y           Z  m.p.                       __________________________________________________________________________                                                       (°C.)               CH.sub.3                                                                         N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH.sub.3    N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.3    N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           NO.sub.2    CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           NO.sub.2    OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           NO.sub.2    OCH.sub.3                                                                            CH.sub.3    N                             H  N(CH.sub.3).sub.2                                                                           NO.sub.2    OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CF.sub.3    CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CF.sub.3    OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CF.sub.3    CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CF.sub.3    OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OCH.sub.3   CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.3   OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.3   CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OCH.sub.3   OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SCH.sub.3   CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SCH.sub.3   OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SCH.sub.3   CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SCH.sub.3   OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SO.sub.2 N(CH.sub.3).sub.2                                                                CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 N(CH.sub.3).sub.2                                                                OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 N(CH.sub.3).sub.2                                                                CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SO.sub.2 N(CH.sub.3).sub.2                                                                OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           SO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CH.sub.2 Cl                                                                     OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CH.sub.2 Cl                                                                     CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OSO.sub.2 CH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OSO.sub.2 CH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OSO.sub.2 CH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OSO.sub.2 CH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CH.sub.2 OCH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CH.sub.2 OCH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CH.sub.2 OCH.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CH.sub.2 OCH.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CHCH.sub. 2                                                                     CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CHCH.sub.2                                                                      OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CHCH.sub.2                                                                      CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CHCH.sub.2                                                                      OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CH.sub.3    CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CH.sub.3    OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CH.sub.3    CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           CH.sub.3    OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           Cl          CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           Cl          OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           Cl          CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           Cl          OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           Br          CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           Br          OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           Br          CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           Br          OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           F           CH.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub. 3).sub.2                                                                          F           OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           F           CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           F           OCH.sub.3                                                                            OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                           H           OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           H           CH.sub.3                                                                             OCH.sub.3   N                             H  N(CH.sub.3).sub.2                                                                            -n-C.sub.4 H.sub.9                                                                       OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.2 CH.sub.3                                                                OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 .sub.-i-C.sub.3 H.sub.7                                                          OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2CH.sub.2 CHCH.sub.2                                                               OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.2 CH.sub.2 Cl                                                             OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.2 CH.sub.2 OCH.sub.3                                                      OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OC.sub.4 H.sub.9                                                                          OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SC.sub.4 H.sub.9                                                                          OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub. 2                                                                          SO.sub.2 N(C.sub.2 H.sub.5).sub.2                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 CH.sub.2 CH.sub.3                                                                OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           SO.sub.2 C.sub.4 H.sub.9                                                                  OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 Br                                                   OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           OSO.sub.2 C.sub.4 H.sub.9                                                                 OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(C.sub.2 H.sub.5).sub.2                                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)C.sub.4 H.sub.9                                                                  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 CF.sub.3                                                                CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.2 CH.sub.2 Cl).sub.2                                                               CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 CH.sub.2 Br                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 CHCH.sub.2                                                              CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                                ##STR64##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(OH)CH.sub.3 CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(OCH.sub.3)CH.sub.3                                                                        CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 OH                                                                      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 OCH.sub.3                                                               CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)(cyclopropyl)                                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)(cyclopentyl)                                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H                                                                                 ##STR65##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H                                                                                 ##STR66##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H                                                                                 ##STR67##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)CH.sub.2 CH.sub.2 OCH.sub.3                                                      CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.3).sub.2                                               CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3)OC.sub. 4 H.sub.9                                                                CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  NHCN          CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H                                                                                 ##STR68##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(OCH.sub.3).sub.2                                                                       CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.3   CH                            H  P(O)(CH.sub.3)OCH.sub.3                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(CH.sub.2 CF.sub.3)OCH.sub.3                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(OCH.sub.3)CH.sub.2 CHCH.sub.2                                                          CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(S)(CH.sub.3)OCH.sub.3                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(CH.sub.3)SCH.sub.3                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(CH.sub.3)NHCH.sub.3                                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H                                                                                 ##STR69##    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(OCH.sub.3)CH.sub.2 CH.sub. 2 OCH.sub.3                                                 CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P(O)(OCH.sub.3)cyclopropyl                                                                  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P.sup.+ (C.sub.6 H.sub.5).sub.3                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P.sup.+ ( -n-C.sub.4 H.sub.9).sub.3                                                         CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  P.sup.+ (CH.sub.3)(C.sub.2 H.sub.5).sub.2                                                   CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SCH.sub.3     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  S -n-C.sub.4 H.sub.9                                                                        CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SC.sub.6 H.sub.5                                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  S(3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  S(4-C.sub.6 H.sub.4 Cl)                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  S(2-C.sub.6 H.sub.4 Br)                                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 CH.sub.3                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 - n-C.sub.4 H.sub.9                                                                CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 C.sub.6 H.sub.5                                                                    CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 (3,4-C.sub.6 H.sub.3 Cl.sub.2)                                                     CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 (4-C.sub.6 H.sub.4 Cl)                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  SO.sub.2 (2-C.sub.6 H.sub.4 Br)                                                             CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  CH.sub.2 NO.sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  CH(CH.sub.3)NO.sub.2                                                                        CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  C(CH.sub.3).sub.2 NO.sub.2                                                                  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  C(CH.sub.3)(C.sub.6 H.sub.5)NO.sub.2                                                        CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  CH(C.sub.4 H.sub.9)NO.sub.2                                                                 CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  CH(4-C.sub.6 H.sub.4 Cl)NO.sub.2                                                            CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  CH(CN).sub.2  CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OC.sub.2 H.sub.5                                                                     CH.sub.3    N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         Cl     OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         F      OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         Br     OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCF.sub.2 H                                                                          CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CF.sub.2 H                                                                           CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.2 CH.sub.2 F                                                                 CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.2 CHF.sub.2                                                                  CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.2 CF.sub.3                                                                   CH.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CF.sub.3                                                                             OCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            H           CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                        CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            NHCH.sub.3  N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            N(CH.sub.3)OCH.sub.3                                                                      N                             H  N(CH.sub.3).sub.2                                                                           CO.sub. 2 CH.sub.3                                                                        OCH.sub.3                                                                            N(CH.sub.3).sub.2                                                                         N                             H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.2 CH.sub.3                                                                         CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CF.sub.3                                                                             CF.sub.3    CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             SCH.sub.3   CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCHCH.sub.2 CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCH.sub.2 CHCH.sub.2                                                                      CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH.sub.2 OCH.sub.2 CH.sub.3                                                               CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 OCH.sub.3                                                              CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         OCH.sub.3                                                                            CH.sub.2 SCH.sub.3                                                                        CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CHO         CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             COCH.sub.3  CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             CH(OCH.sub.3).sub.2                                                                       CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                              ##STR70##  CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             OCF.sub.2 H CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             SCF.sub.2 H CH                            H  N(CH.sub.3).sub.2                                                                           CO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                             cyclopropyl CH                            __________________________________________________________________________

                                      TABLE VIII                                  __________________________________________________________________________    General Formula VIII                                                                                                                   m.p.                 Q  R  R.sub.2                                                                            R.sub.4                                                                              R.sub.5 R.sub.6                                                                           R.sub.9                                                                              R.sub.12                                                                            R.sub.13                                                                             R.sub.14                                                                             (°C.)         __________________________________________________________________________    Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHC.sub.6 H.sub.5                                                                   --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     CH.sub.3                                                                            --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     OCH.sub.3                                                                           --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --                          Q-1                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHCH.sub.3                                                                          --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             CH.sub.3                                                                            --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  C.sub.6 H.sub.5                                                                      CH.sub.3                                                                            --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.2                                                                             OCH.sub.3                                                                           --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             NHCH.sub.3                                                                          --     --                          Q-2                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             NHC.sub.6 H.sub.5                                                                   --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     CH.sub.3                                                                            --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     OCH.sub.3                                                                           --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --                          Q-3                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHCH.sub.3                                                                          --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     CH.sub.3                                                                            --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     OCH.sub. 3                                                                          --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     O-- .sub.-t-C.sub.4 H.sub.9                                                         --     --                          Q-4                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     NHCH.sub.3                                                                          --     --                          Q-5                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    --     --                          Q-6                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    --     --                          Q-7                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    --     --                          Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      H                           Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      4-CH.sub.3                  Q-8                                                                              H  CO.sub.3 CH.sub.3                                                                  --     --      --  --     --    H      4-OCH.sub.3                 Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      3-SCH.sub.3                 Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-Cl   4-Cl                        Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      4-CO.sub.2 CH.sub.3         Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-OCH.sub.3                                                                          5-OCH.sub.3                 Q-8                                                                              H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-F    5-NHCOCH.sub.3              Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    H      H      221-231              Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-NHCOCH.sub.3                                                                       H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-Cl   H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-OCH.sub.3                                                                          H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    2-SCH.sub.3                                                                          H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  C.sub.2 H.sub.5                                                                      C.sub.2 H.sub.5                                                                       --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.2 CH═CH.sub.2                                                              --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 Cl                                                                 CH.sub.2 CH.sub.2 Cl                                                                  --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 OH                                                                 CH.sub.2 CH.sub.2 OH                                                                  --  --     --    H      H                           Q-9                                                                              H  CO.sub.2 CH.sub.3                                                                  --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                    --  --     --    H      H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-NHCOCH.sub.3                                                                       H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-Cl   H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-OCH.sub.3                                                                          H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    2-SCH.sub.3                                                                          H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-CO.sub.2 CH.sub.3                                                                  H                           Q-10                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-Cl   5-Cl                        Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-NHCOCH.sub.3                                                                       H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-Cl   H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-OCH.sub.3                                                                          H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                              --  --     --    4-SCH.sub.3                                                                          H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  C.sub.2 H.sub.5                                                                      C.sub.2 H.sub.5                                                                       --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.2 CH═CH.sub.2                                                              --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 Cl                                                                 CH.sub.2 CH.sub.2 Cl                                                                  --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  CH.sub.2 CH.sub.2 OH                                                                 CH.sub. 2 CH.sub.2 OH                                                                 --  --     --    H      H                           Q-11                                                                             H  CO.sub.2 CH.sub.3                                                                  --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --                                                    --  --     --    H      H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    H      H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-NHCOCH.sub.3                                                                       H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-Cl   H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-OCH.sub.3                                                                          H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-SCH.sub.3                                                                          H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    4-CO.sub.2 CH.sub.3                                                                  H                           Q-12                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  --     --    3-Cl   5-Cl                        Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          H      --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      C.sub.4 H.sub.9                                                                   CH.sub.3                                                                             --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          C.sub.6 H.sub.5                                                                      --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          4-C.sub.6 H.sub.4 Cl                                                                 --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          2,4-C.sub.6 H.sub.3 Cl.sub.2                                                         --    --     --                          Q-13                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      CH.sub.3                                                                          CH.sub.3                                                                             --    --     --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    H      --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  C.sub.6 H.sub.5                                                                      --    H      --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  4-C.sub.6 H.sub.4 Cl                                                                 --    H      --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    CH.sub.3                                                                             --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    Cl     --                          Q-14                                                                             H  CO.sub.2 CH.sub.3                                                                  --     --      --  CH.sub.3                                                                             --    OCH.sub.3                                                                            --                          __________________________________________________________________________

                  TABLE IX                                                        ______________________________________                                        General Formula IX                                                                                                      m.p.                                R    R.sub.1        R.sub.2   X.sub.1                                                                              Y.sub.1                                                                            (°C.)                        ______________________________________                                        H    N(CH.sub.3).sub.2                                                                            H         CH.sub.3                                                                             O                                        H    N(CH.sub.3).sub.2                                                                            H         CH.sub.3                                                                             CH.sub.2                                 H    N(CH.sub.3).sub.2                                                                            H         OCH.sub.3                                                                            O                                        H    N(CH.sub.3).sub.2                                                                            H         OCH.sub.3                                                                            CH.sub.2                                 H    N(CH.sub.3).sub.2                                                                            H         OC.sub.2 H.sub.5                                                                     O                                        H    N(CH.sub.3).sub.2                                                                            H         OC.sub.2 H.sub.5                                                                     CH.sub.2                                 H    N(CH.sub.3).sub.2                                                                            H         OCF.sub.2 H                                                                          O                                        H    N(CH.sub.3).sub.2                                                                            H         OCF.sub.2 H                                                                          CH.sub.2                                 CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                            H         OCH.sub.3                                                                            O                                        H    N(CH.sub.3).sub.2                                                                            6-Cl      CH.sub.3                                                                             O                                        H    N(CH.sub.3).sub.2                                                                            5-OCH.sub.3                                                                             CH.sub.3                                                                             O                                        H    N(CH.sub.3).sub.2                                                                            5-SCH.sub.3                                                                             CH.sub.3                                                                             O                                        H    N(CH.sub.3).sub.2                                                                            5-N(CH.sub.3).sub.2                                                                     CH.sub.3                                                                             O                                        H    N(CH.sub.3).sub.2                                                                            5-NO.sub.2                                                                              CH.sub.3                                                                             O                                        H    N(CH.sub.3).sub.2                                                                            6-CH.sub.3                                                                              CH.sub.3                                                                             O                                        H    N(CH.sub.3).sub.2                                                                            6-CF.sub.3                                                                              CH.sub.3                                                                             O                                        H    N(CH.sub.3)C.sub.4 H.sub.9                                                                   H         CH.sub.3                                                                             O                                        H    N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                          H         CH.sub.3                                                                             O                                        H    N(OH)CH.sub.3  H         CH.sub.3                                                                             O                                        H    N(CH.sub.3)CH.sub.2 OH                                                                       H         CH.sub.3                                                                             O                                        H    NHCN           H         CH.sub.3                                                                             O                                        H    P(O)(OCH.sub.3).sub.2                                                                        H         CH.sub.3                                                                             O                                        H    P(O)(CH.sub.3)OCH.sub.3                                                                      H         CH.sub.3                                                                             O                                        H    P(O)(CH.sub.3)OCH.sub.3                                                                      H         CH.sub.3                                                                             O                                        H    P(S)(CH.sub.3)OCH.sub.3                                                                      H         CH.sub.3                                                                             O                                        H    P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              H         CH.sub.3                                                                             O                                        H    SCH.sub.3      H         CH.sub.3                                                                             O                                        H    SO.sub.2 CH.sub.3                                                                            H         CH.sub.3                                                                             O                                        H    CH.sub.2 NO.sub.2                                                                            H         CH.sub.3                                                                             O                                        H    CH(CN).sub.2   H         CH.sub.3                                                                             O                                        ______________________________________                                    

                  TABLE X                                                         ______________________________________                                        General Formula X                                                                                                             m.p.                          Q    R     R.sub.2                                                                             R.sub.4                                                                            R.sub.5                                                                            R.sub.6                                                                            R.sub.9                                                                            R.sub.12                                                                            R.sub.13                                                                           R.sub.14  (°C.)        ______________________________________                                        Q-1  H     H     --   --   --   --   OCH.sub.3                                                                           --   --                            Q-1  H     H     --   --   --   --   CH.sub.3                                                                            --   --                            Q-2  H     H     --   --   --   CH.sub.3                                                                           OCH.sub.3                                                                           --   --                            Q-2  H     H     --   --   --   CH.sub.3                                                                           CH.sub.3                                                                            --   --                            Q-3  H     H     --   --   --   --   OCH.sub.3                                                                           --   --                            Q-3  H     H     --   --   --   --   CH.sub.3                                                                            --   --                            Q-4  H     H     --   --   --   --   OCH.sub.3                                                                           --   --                            Q-4  H     H     --   --   --   --   CH.sub.3                                                                            --   --                            Q-5  H     H     --   --   --   --   --    --   --                            Q-6  H     H     --   --   --   --   --    --   --                            Q-7  H     H     --   --   --   --   --    --   --                            Q-8  H     H     --   --   --   --   --    H    H                             Q-9  H     H     CH.sub.3                                                                           CH.sub.3                                                                           --   --   --    H    H                             Q-10 H     H     --   --   --   --   --    H    H                             Q-11 H     H     CH.sub.3                                                                           CH.sub.3                                                                           --   --   --    CH.sub.3                                                                           H                             Q-12 H     H     --   --   --   --   --    CH.sub.3                                                                           H                             Q-13 H     H     --   --   CH.sub.3                                                                           CH.sub.3                                                                           --    --   --                            Q-14 H     H     --   --   CH.sub.3                                                                           CH.sub.3                                                                           --    --   --                            ______________________________________                                    

                  TABLE XI                                                        ______________________________________                                        General Formula XI                                                                                                     m.p.                                 R   R.sub.1        R.sub.2      X.sub.1                                                                            Y.sub.1                                                                           (°C.)                         ______________________________________                                        H   N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            NO.sub.2     CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            CF.sub.3     CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            OCH.sub.3    CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            SCH.sub.3    CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH═CH.sub.2                                                                  CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            CH.sub.3     CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            Cl           CH.sub.3                                                                           O                                        H   N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                          CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   NHCN           CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        ______________________________________                                    

                  TABLE XII                                                       ______________________________________                                        General Formula XII                                                                                                   m.p.                                  Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                             R.sub.14            (°C.)                          ______________________________________                                        Q-1  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-1  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 OCH.sub.3 ----                             Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 CH.sub.3 ----                              Q-3  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-3  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-4  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-5  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-6  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-7  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-8  H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-9  H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------HH                                Q-10 H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-11 H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------CH.sub.3 H                        Q-12 H     CO.sub.2 CH.sub.3                                                                      ----------CH.sub.3 H                                      Q-13 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              Q-14 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              ______________________________________                                    

                  TABLE XIII                                                      ______________________________________                                        General Formula XIII                                                                                                   m.p.                                 R   R.sub.1        R.sub.2      X.sub.1                                                                            Y.sub.1                                                                           (°C.)                         ______________________________________                                        H   N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            NO.sub.2     CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            CF.sub.3     CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            OCH.sub.3    CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            SCH.sub.3    CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH═CH.sub.2                                                                  CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            CH.sub.3     CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            Cl           CH.sub.3                                                                           O                                        H   N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                          CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   NHCN           CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        ______________________________________                                    

                  TABLE XIV                                                       ______________________________________                                        General Formula XIV                                                                                                   m.p.                                  Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                             R.sub.14            (°C.)                          ______________________________________                                        Q-1  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-1  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 OCH.sub.3 ----                             Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 CH.sub.3 ----                              Q-3  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-3  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-4  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-5  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-6  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-7  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-8  H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-9  H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------HH                                Q-10 H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-11 H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------CH.sub.3 H                        Q-12 H     CO.sub.2 CH.sub.3                                                                      ----------CH.sub.3 H                                      Q-13 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              Q-14 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              ______________________________________                                    

                  TABLE XV                                                        ______________________________________                                        General Formula XV                                                                                                     m.p.                                 R   R.sub.1        R.sub.2      X.sub.1                                                                            Y.sub.1                                                                           (°C.)                         ______________________________________                                        H   N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            NO.sub.2     CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            CF.sub.3     CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            OCH.sub.3    CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            SCH.sub.3    CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH═CH.sub.2                                                                  CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            CH.sub.3     CH.sub.3                                                                           O                                        H   N(CH.sub.3).sub.2                                                                            Cl           CH.sub.3                                                                           O                                        H   N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                          CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   NHCN           CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           O                                        ______________________________________                                    

                  TABLE XVI                                                       ______________________________________                                        General Formula XVI                                                                                                   m.p.                                  Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                             R.sub.14            (°C.)                          ______________________________________                                        Q-1  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-1  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 OCH.sub.3 ----                             Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 CH.sub.3 ----                              Q-3  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-3  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-4  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-5  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-6  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-7  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-8  H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-9  H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------HH                                Q-10 H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-11 H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------CH.sub.3 H                        Q-12 H     CO.sub.2 CH.sub.3                                                                      ----------CH.sub.3 H                                      Q-13 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              Q-14 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              ______________________________________                                    

                  TABLE XVII                                                      ______________________________________                                        General Formula XVII                                                                                                    m.p.                                R    R.sub.1        R.sub.2   X.sub.1                                                                              Y.sub.2                                                                            (°C.)                        ______________________________________                                        H    N(CH.sub.3).sub.2                                                                            H         CH.sub.3                                                                             H                                        H    N(CH.sub.3).sub.2                                                                            H         CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3).sub.2                                                                            H         OCH.sub.3                                                                            H                                        H    N(CH.sub.3).sub.2                                                                            H         OCH.sub.3                                                                            CH.sub.3                                 H    N(CH.sub.3).sub.2                                                                            H         OC.sub.2 H.sub.5                                                                     H                                        H    N(CH.sub.3).sub.2                                                                            H         OC.sub.2 H.sub.5                                                                     CH.sub.3                                 H    N(CH.sub.3).sub.2                                                                            H         OCF.sub.2 H                                                                          H                                        H    N(CH.sub.3).sub.2                                                                            H         OCF.sub.2 H                                                                          CH.sub.3                                 CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                            H         CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3).sub.2                                                                            6-Cl      CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3).sub.2                                                                            5-OCH.sub.3                                                                             CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3).sub.2                                                                            5-SCH.sub.3                                                                             CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3).sub.2                                                                            5-N(CH.sub.3).sub.2                                                                     CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3).sub.2                                                                            5-NO.sub.2                                                                              CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3).sub.2                                                                            6-CH.sub.3                                                                              CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3 ).sub.2                                                                           6-CF.sub.3                                                                              CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3)C.sub.4 H.sub.9                                                                   H         CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                          H         CH.sub.3                                                                             CH.sub.3                                 H    N(OH)CH.sub.3  H         CH.sub.3                                                                             CH.sub.3                                 H    N(CH.sub.3)CH.sub.2 OH                                                                       H         CH.sub.3                                                                             CH.sub.3                                 H    NHCN           H         CH.sub.3                                                                             CH.sub.3                                 H    P(O)(OCH.sub.3).sub.2                                                                        H         CH.sub.3                                                                             CH.sub.3                                 H    P(O)(CH.sub.3)OCH.sub.3                                                                      H         CH.sub.3                                                                             CH.sub.3                                 H    P(O)(CH.sub.3)OCH.sub.3                                                                      H         CH.sub.3                                                                             CH.sub.3                                 H    P(S)(CH.sub.3)OCH.sub.3                                                                      H         CH.sub.3                                                                             CH.sub.3                                 H    P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              H         CH.sub.3                                                                             CH.sub.3                                 H    SCH.sub.3      H         CH.sub.3                                                                             CH.sub.3                                 H    SO.sub.2 CH.sub.3                                                                            H         CH.sub.3                                                                             CH.sub.3                                 H    CH.sub.2 NO.sub.2                                                                            H         CH.sub.3                                                                             CH.sub.3                                 H    CH(CN).sub.2   H         CH.sub.3                                                                             CH.sub.3                                 ______________________________________                                    

                  TABLE XVIII                                                     ______________________________________                                        General Formula XVIII                                                                                                         m.p.                          Q    R     R.sub.2                                                                             R.sub.4                                                                            R.sub.5                                                                            R.sub.6                                                                            R.sub.9                                                                            R.sub.12                                                                            R.sub.13                                                                           R.sub.14  (°C.)        ______________________________________                                        Q-1  H     H     --   --   --   --   OCH.sub.3                                                                           --   --                            Q-1  H     H     --   --   --   --   CH.sub.3                                                                            --   --                            Q-2  H     H     --   --   --   CH.sub.3                                                                           OCH.sub.3                                                                           --   --                            Q-2  H     H     --   --   --   CH.sub.3                                                                           CH.sub.3                                                                            --   --                            Q-3  H     H     --   --   --   --   OCH.sub.3                                                                           --   --                            Q-3  H     H     --   --   --   --   CH.sub.3                                                                            --   --                            Q-4  H     H     --   --   --   --   OCH.sub.3                                                                           --   --                            Q-4  H     H     --   --   --   --   CH.sub.3                                                                            --   --                            Q-5  H     H     --   --   --   --   --    --   --                            Q-6  H     H     --   --   --   --   --    --   --                            Q-7  H     H     --   --   --   --   --    --   --                            Q-8  H     H     --   --   --   --   --    H    H                             Q-9  H     H     CH.sub.3                                                                           CH.sub.3                                                                           --   --   --    H    H                             Q-10 H     H     --   --   --   --   --    H    H                             Q-11 H     H     CH.sub.3                                                                           CH.sub.3                                                                           --   --   --    CH.sub.3                                                                           H                             Q-12 H     H     --   --   --   --   --    CH.sub.3                                                                           H                             Q-13 H     H     --   --   CH.sub.3                                                                           CH.sub.3                                                                           --    --   --                            Q-14 H     H     --   --   CH.sub.3                                                                           CH.sub.3                                                                           --    --   --                            ______________________________________                                    

                  TABLE XIX                                                       ______________________________________                                        General Formula XIX                                                                                                     m.p.                                R   R.sub.1        R.sub.2      X.sub.1                                                                            Y.sub.2                                                                            (°C.)                        ______________________________________                                        H   N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            NO.sub.2     CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            CF.sub.3     CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            OCH.sub.3    CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            SCH.sub.3    CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH═CH.sub.2                                                                  CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            CH.sub.3     CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            Cl           CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub. 3)CH.sub.2 CH═CH.sub.2                                                         CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   NHCN           CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 ______________________________________                                    

                  TABLE XX                                                        ______________________________________                                        General Formula XX                                                                                                    m.p.                                  Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                             R.sub.14            (°C.)                          ______________________________________                                        Q-1  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-1  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 OCH.sub.3 ----                             Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 CH.sub.3 ----                              Q-3  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-3  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-4  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-5  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-6  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-7  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-8  H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-9  H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------HH                                Q-10 H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-11 H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------CH.sub.3 H                        Q-12 H     CO.sub.2 CH.sub.3                                                                      ----------CH.sub.3 H                                      Q-13 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              Q-14 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              ______________________________________                                    

                  TABLE XXI                                                       ______________________________________                                        General Formula XXI                                                                                                     m.p.                                R   R.sub.1        R.sub.2      X.sub.1                                                                            Y.sub.2                                                                            (°C.)                        ______________________________________                                        H   N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            NO.sub.2     CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            CF.sub.3     CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            OCH.sub.3    CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            SCH.sub.3    CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH═CH.sub.2                                                                  CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            CH.sub.3     CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            Cl           CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub. 3)CH.sub.2 CH═CH.sub.2                                                         CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   NHCN           CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 ______________________________________                                    

                  TABLE XXII                                                      ______________________________________                                        General Formula XXII                                                                                                  m.p.                                  Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                             R.sub.14            (°C.)                          ______________________________________                                        Q-1  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-1  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 OCH.sub.3 ----                             Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 CH.sub.3 ----                              Q-3  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-3  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-4  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-5  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-6  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-7  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-8  H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-9  H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------HH                                Q-10 H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-11 H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------CH.sub.3 H                        Q-12 H     CO.sub.2 CH.sub.3                                                                      ----------CH.sub.3 H                                      Q-13 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              Q-14 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              ______________________________________                                    

                  TABLE XXIII                                                     ______________________________________                                        General Formula XXIII                                                                                                   m.p.                                R   R.sub.1        R.sub.2      X.sub.1                                                                            Y.sub.2                                                                            (°C.)                        ______________________________________                                        H   N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            NO.sub.2     CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            CF.sub.3     CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            OCH.sub.3    CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            SCH.sub.3    CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH═CH.sub.2                                                                  CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            CH.sub.3     CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3).sub.2                                                                            Cl           CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub. 3)CH.sub.2 CH═CH.sub.2                                                         CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   NHCN           CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                 ______________________________________                                    

                  TABLE XXIV                                                      ______________________________________                                        General Formula XXIV                                                                                                  m.p.                                  Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                             R.sub.14            (°C.)                          ______________________________________                                        Q-1  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-1  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 OCH.sub.3 ----                             Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 CH.sub.3 ----                              Q-3  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-3  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-4  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-5  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-6  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-7  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-8  H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-9  H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------HH                                Q-10 H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-11 H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------CH.sub.3 H                        Q-12 H     CO.sub.2 CH.sub.3                                                                      ----------CH.sub.3 H                                      Q-13 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              Q-14 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              ______________________________________                                    

                  TABLE XXV                                                       ______________________________________                                        General Formula XXV                                                           R    R.sub.1        R.sub.2   X.sub.1                                                                              m.p.(°C.)                         ______________________________________                                        H    N(CH.sub.3).sub.2                                                                            H         CH.sub.3                                        H    N(CH.sub.3).sub.2                                                                            H         OCH.sub.3                                       H    N(CH.sub.3).sub.2                                                                            H         OC.sub.2 H.sub.5                                H    N(CH.sub.3).sub.2                                                                            H         OCF.sub.2 H                                     H    N(CH.sub.3).sub.2                                                                            H         OCH.sub.3                                       H    N(CH.sub.3).sub.2                                                                            6-Cl      CH.sub.3                                        H    N(CH.sub.3).sub.2                                                                            5-OCH.sub.3                                                                             CH.sub.3                                        H    N(CH.sub.3).sub.2                                                                            5-SCH.sub.3                                                                             CH.sub.3                                        H    N(CH.sub.3).sub.2                                                                            5-N(CH.sub.3).sub.2                                                                     CH.sub.3                                        H    N(CH.sub.3).sub.2                                                                            5-NO.sub.2                                                                              CH.sub.3                                        H    N(CH.sub.3).sub.2                                                                            6-CH.sub.3                                                                              CH.sub.3                                        H    N(CH.sub.3)C.sub.4 H.sub.9                                                                   6-CF.sub.3                                                                              CH.sub.3                                        H    N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                          H         CH.sub.3                                        H    N(OH)CH.sub.3  H         CH.sub.3                                        H    N(CH.sub.3)CH.sub.2 OH                                                                       H         CH.sub.3                                        H    NHCN           H         CH.sub.3                                        H    P(O)(OCH.sub.3).sub.2                                                                        H         CH.sub.3                                        H    P(O)(CH.sub.3)OCH.sub.3                                                                      H         CH.sub.3                                        H    P(O)(CH.sub.3)OCH.sub.3                                                                      H         CH.sub.3                                        H    P(S)(CH.sub.3)OCH.sub.3                                                                      H         CH.sub.3                                        H    P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              H         CH.sub.3                                        H    SCH.sub.3      H         CH.sub.3                                        H    SO.sub.2 CH.sub.3                                                                            H         CH.sub.3                                        H    CH.sub.2 NO.sub.2                                                                            H         CH.sub.3                                        H    CH(CN).sub.2   H         CH.sub.3                                        ______________________________________                                    

                  TABLE XXVI                                                      ______________________________________                                        General Formula XXVI                                                                                                          m.p.                          Q    R     R.sub.2                                                                             R.sub.4                                                                            R.sub.5                                                                            R.sub.6                                                                            R.sub.9                                                                            R.sub.12                                                                            R.sub.13                                                                           R.sub.14  (°C.)        ______________________________________                                        Q-1  H     H     --   --   --   --   OCH.sub.3                                                                           --   --                            Q-1  H     H     --   --   --   --   CH.sub.3                                                                            --   --                            Q-2  H     H     --   --   --   CH.sub.3                                                                           OCH.sub.3                                                                           --   --                            Q-2  H     H     --   --   --   CH.sub.3                                                                           CH.sub.3                                                                            --   --                            Q-3  H     H     --   --   --   --   OCH.sub.3                                                                           --   --                            Q-3  H     H     --   --   --   --   CH.sub.3                                                                            --   --                            Q-4  H     H     --   --   --   --   OCH.sub.3                                                                           --   --                            Q-4  H     H     --   --   --   --   CH.sub.3                                                                            --   --                            Q-5  H     H     --   --   --   --   --    --   --                            Q-6  H     H     --   --   --   --   --    --   --                            Q-7  H     H     --   --   --   --   --    --   --                            Q-8  H     H     --   --   --   --   --    H    H                             Q-9  H     H     CH.sub.3                                                                           CH.sub.3                                                                           --   --   --    H    H                             Q-10 H     H     --   --   --   --   --    H    H                             Q-11 H     H     CH.sub.3                                                                           CH.sub.3                                                                           --   --   --    CH.sub.3                                                                           H                             Q-12 H     H     --   --   --   --   --    CH.sub.3                                                                           H                             Q-13 H     H     --   --   CH.sub.3                                                                           CH.sub.3                                                                           --    --   --                            Q-14 H     H     --   --   CH.sub.3                                                                           CH.sub.3                                                                           --    --   --                            ______________________________________                                    

                  TABLE XXVII                                                     ______________________________________                                        General Formula XXVII                                                         R   R.sub.1        R.sub.2      X.sub.1                                                                            m.p.(°C.)                         ______________________________________                                        H   N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            NO.sub.2     CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            CF.sub.3     CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            OCH.sub.3    CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            SCH.sub.3    CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH═CH.sub.2                                                                  CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            CH.sub.3     CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            Cl           CH.sub.3                                      H   N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                          CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   NHCN           CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub. 3                                                                         CH.sub.3                                      H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      ______________________________________                                    

                  TABLE XXVIII                                                    ______________________________________                                        General Formula XXVIII                                                                                                m.p.                                  Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                             R.sub.14            (°C.)                          ______________________________________                                        Q-1  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-1  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 OCH.sub.3 ----                             Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 CH.sub.3 ----                              Q-3  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-3  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-4  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-5  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-6  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-7  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-8  H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-9  H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------HH                                Q-10 H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-11 H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------CH.sub.3 H                        Q-12 H     CO.sub.2 CH.sub.3                                                                      ----------CH.sub.3 H                                      Q-13 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              Q-14 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              ______________________________________                                    

                  TABLE XXIX                                                      ______________________________________                                        General Formula XXIX                                                          R   R.sub.1        R.sub.2      X.sub.1                                                                            m.p.(°C.)                         ______________________________________                                        H   N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            NO.sub.2     CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            CF.sub.3     CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            OCH.sub.3    CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            SCH.sub.3    CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH═CH.sub.2                                                                  CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            CH.sub.3     CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            Cl           CH.sub.3                                      H   N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                          CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   NHCN           CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub. 3                                                                         CH.sub.3                                      H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      ______________________________________                                    

                  TABLE XXX                                                       ______________________________________                                        General Formula XXX                                                                                                   m.p.                                  Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                             R.sub.14            (°C.)                          ______________________________________                                        Q-1  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-1  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 OCH.sub.3 ----                             Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 CH.sub.3 ----                              Q-3  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-3  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-4  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-5  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-6  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-7  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-8  H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-9  H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------HH                                Q-10 H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-11 H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------CH.sub.3 H                        Q-12 H     CO.sub.2 CH.sub.3                                                                      ----------CH.sub.3 H                                      Q-13 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              Q-14 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              ______________________________________                                    

                  TABLE XXXI                                                      ______________________________________                                        General Formula XXXI                                                          R   R.sub.1        R.sub.2      X.sub.1                                                                            m.p.(°C.)                         ______________________________________                                        H   N(CH.sub.3).sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            NO.sub.2     CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            CF.sub.3     CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            OCH.sub.3    CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            SCH.sub.3    CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            SO.sub.2 N(CH.sub.3).sub.2                                                                 CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            SO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            OSO.sub.2 CH.sub.3                                                                         CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            OCH.sub.2 CH═CH.sub.2                                                                  CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            CH.sub.3     CH.sub.3                                      H   N(CH.sub.3).sub.2                                                                            Cl           CH.sub.3                                      H   N(CH.sub.3)C.sub.4 H.sub.9                                                                   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3)CH.sub.2 CH═CH.sub.2                                                          CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(OH)CH.sub.3  CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   N(CH.sub.3)CH.sub.2 OH                                                                       CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   NHCN           CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   P(O)(OCH.sub.3).sub.2                                                                        CO.sub.2 CH.sub. 3                                                                         CH.sub.3                                      H   P(O)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   P(S)(CH.sub.3)OCH.sub.3                                                                      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   P.sup.+ (C.sub.6 H.sub.5).sub.3                                                              CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   SCH.sub.3      CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   SO.sub.2 CH.sub.3                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   CH.sub.2 NO.sub.2                                                                            CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      H   CH(CN).sub.2   CO.sub.2 CH.sub.3                                                                          CH.sub.3                                      ______________________________________                                    

                  TABLE XXXII                                                     ______________________________________                                        General Formula XXXII                                                                                                 m.p.                                  Q    R     R.sub.3  R.sub.4 R.sub.5 R.sub.6 R.sub.9 R.sub.12 R.sub.13                             R.sub.14            (°C.)                          ______________________________________                                        Q-1  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-1  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 OCH.sub.3 ----                             Q-2  H     CO.sub.2 CH.sub.3                                                                      ------CH.sub.3 CH.sub.3 ----                              Q-3  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-3  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-4  H     CO.sub.2 CH.sub.3                                                                      --------OCH.sub.3 ----                                    Q-4  H     CO.sub.2 CH.sub.3                                                                      --------CH.sub.3 ----                                     Q-5  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-6  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-7  H     CO.sub.2 CH.sub.3                                                                      --------------                                            Q-8  H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-9  H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------HH                                Q-10 H     CO.sub.2 CH.sub.3                                                                      ----------HH                                              Q-11 H     CO.sub.2 CH.sub.3                                                                      CH.sub.3 CH.sub.3 ------CH.sub.3 H                        Q-12 H     CO.sub.2 CH.sub.3                                                                      ----------CH.sub.3 H                                      Q-13 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              Q-14 H     CO.sub.2 CH.sub.3                                                                      ----CH.sub.3 CH.sub.3 ------                              ______________________________________                                    

FORMULATIONS

Useful formulations of the compounds of Formula I and II can be preparedin conventional ways. They include dusts, granules, pellets, solutions,suspensions, emulsions, wettable powders, emulsifiable concentrates andthe like. Many of these may be applied directly. Sprayable formulationscan be extended in suitable media and used at spray volumes of from afew liters to several hundred liters per hectare. High strengthcompositions are primarily used as intermediates for furtherformulation. The formulations, broadly, contain about 0.1% to 99% byweight of active ingredient(s) and at least one of (a) about 0.1% to 20%surfactant(s) and (b) about 1% to 99.9% solid or liquid inertdiluent(s). More specifically, they will contain these ingredients inthe following approximate proportions:

                  TABLE XXXIII                                                    ______________________________________                                                    Active  Weight Percent*                                                       Ingredient                                                                            Diluent(s)                                                                              Surfactant(s)                                   ______________________________________                                        Wettable Powders                                                                            20-90      0-74     1-10                                        Oil Suspensions,                                                                             3-50     40-95     0-15                                        Emulsions, Solutions,                                                         (including Emulsifiable                                                       Concentrates)                                                                 Aqueous Suspension                                                                          10-50     40-84     1-20                                        Dusts          1-25     70-99     0-5                                         Granules and Pellets                                                                        0.1-95      5-99.9  0-15                                        High Strength 90-99      0-10     0-2                                         Compositions                                                                  ______________________________________                                         *Active ingredient plus at least one of a Surfactant or a Diluent equals      100 weight percent.                                                      

Lower or higher levels of active ingredient can, of course, be presentdepending on the intended use and the physical properties of thecompound. Higher ratios of surfactant to active ingredient are sometimesdesirable, and are achieved by incorporation into the formulation or bytank mixing.

Typical solid diluents are described in Watkins, et al., "Handbook ofInsecticide Dust Diluents and Carriers", 2nd Ed., Dorland Books,Caldwell, N.J., but other solids, either mined or manufactured, may beused. The more absorptive diluents are preferred for wettable powdersand the denser ones for dusts. Typical liquid diluents and solvents aredescribed in Marsden, "Solvents Guide," 2nd Ed., Interscience, New York,1950. Solubility under 0.1% is preferred for suspension concentrates;solution concentrates are preferably stable against phase separation at0° C. "McCutcheon's Detergents and Emulsifiers Annual", MC PublishingCorp., Ridgewood, N.J., as well as Sisely and Wood, "Encyclopedia ofSurface Active Agents", Chemical Publishing Co., Inc., New York, 1964,list surfactants and recommended uses. All formulations can containminor amounts of additives to reduce foaming, caking, corrosion,microbiological growth, etc.

The methods of making such compositions are well known. Solutions areprepared by simply mixing the ingredients. Fine solid compositions aremade by blending and, usually, grinding as in a hammer or fluid energymill. Suspensions are prepared by wet milling (see, for example,Littler, U.S. Pat. No. 3,060,084). Granules and pellets may be made byspraying the active material upon preformed granular carriers or byagglomeration techniques. See J. E. Browning, "Agglomeration", ChemicalEngineering, Dec. 4, 1967, pp. 147ff. and "Perry's Chemical Engineer'sHandbook", 5th Ed., McGraw-Hill, New York, 1973, pp. 8-57ff.

For further information regarding the art of formulation, see forexample:

H. M. Loux, U.S. Pat. No. 3,235,361, Feb. 15, 1966, Col. 6, line 16through Col. 7, line 19 and Examples 10 through 41;

R. W. Luckenbaugh, U.S. Pat. No. 3,309,192, Mar. 14, 1967, Col. 5, line43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58,132, 138-140, 162-164, 166, 167 and 169-182;

H. Gysin and E. Knusli, U.S. Pat. No. 2,891,855, June 23, 1959, Col. 3,line 66 through Col. 5, line 17 and Examples 1-4;

G. C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc.,New York, 1961, pp. 81-96; and

J. D. Fryer and S. A. Evans, "Weed Control Handbook", 5th Ed., BlackwellScientific Publications, Oxford, 1968, pp. 101-103.

In the following examples, all parts are by weight unless otherwiseindicated.

EXAMPLE 4 Wettable Powder

2-[4-(dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide:80%

sodium alkylnaphthalenesulfonate: 2%

sodium ligninsulfonate: 2%

synthetic amorphous silica: 3%

kaolinite: 13%

The ingredients are blended, hammer-milled until all the solids areessentially under 50 microns, reblended, and packaged.

EXAMPLE 5 Wettable Powder

[[2-[[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]phenyl]azo]phosphonicacid, dimethylester: 50%

sodium alkylnaphthalenesulfonate: 2%

low viscosity methyl cellulose: 2%

diatomaceous earth: 46%

The ingredients are blended, coarsely hammer-milled and then air-milledto produce particles essentially all below 10 microns in diameter. Theproduct is reblended before packaging.

EXAMPLE 6 Granule

Wettable Powder of Example 5: 5%

attapulgite granules: 95%

(U.S.S. 20-40 mesh; 0.84-0.42 mm)

A slurry of wettable powder containing 25% solids is sprayed on thesurface of attapulgite granules in a double-cone blender. The granulesare dried and packaged.

EXAMPLE 7 Extruded Pellet

2-(dimethyl-1-triazeno)-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide:25%

anhydrous sodium sulfate: 10%

crude calcium ligninsulfonate: 5%

sodium alkylnaphthalenesulfonate: 1%

calcium/magnesium bentonite: 59%

The ingredients are blended, hammer-milled and then moistened with about12% water. The mixture is extruded as cylinders about 3 mm diameterwhich are cut to produce pellets about 3 mm long. These may be useddirectly after drying, or the dried pellets may be crushed to pass aU.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S.No. 40 sieve (0.42 mm openings) may be packaged for use and the finesrecycled.

EXAMPLE 8 Oil Suspension

[[2-[[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]phenyl]azo]phosphonicacid, dimethylester: 25%

polyoxyethylene sorbitol hexaoleate: 5%

highly aliphatic hydrocarbon oil: 70%

The ingredients are ground together in a sand mill until the solidparticles have been reduced to under about 5 microns. The resultingthick suspension may be applied directly, but preferably after beingextended with oils or emulsified in water.

EXAMPLE 9 Wettable Powder

2-(dimethyl-1-triazeno)-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide:20%

sodium alkylnaphthalenesulfonate: 4%

sodium ligninsulfonate: 4%

low viscosity methyl cellulose: 3%

attapulgite: 69%

The ingredients are thoroughly blended. After grinding in a hammer-millto produce particles essentially all below 100 microns, the material isreblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) andpackaged.

EXAMPLE 10 Low Strength Granule

2-(dimethyl-1-triazeno)-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide:1%

N,N-dimethylformamide: 9%

attapulgite granules: 90%

(U.S.S. 20-40 sieve)

The active ingredient is dissolved in the solvent and the solution issprayed upon dedusted granules in a double cone blender. After sprayingof the solution has been completed, the blender is allowed to run for ashort period and then the granules are packaged.

EXAMPLE 11 Aqueous Suspension

2-[4-(dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide:40%

polyacrylic acid thickener: 0.3%

dodecylphenol polyethylene glycol ether: 0.5%

disodium phosphate: 1%

monosodium phosphate: 0.5%

polyvinyl alcohol: 1.0%

water: 56.7%

The ingredients are blended and ground together in a sand mill toproduce particles essentially all under 5 microns in size.

EXAMPLE 12 Solution

[[2-[[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]phenyl]azo]phosphonicacid, dimethylester, sodium salt: 5%

water: 95%

The salt is added directly to the water with stirring to produce thesolution, which may then be packaged for use.

EXAMPLE 13 Low Strength Granule

2-[4-(dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide:0.1%

attapulgite granules: 99.9%

(U.S.S. 20-40 mesh)

The active ingredient is dissolved in a solvent and the solution issprayed upon dedusted granules in a double-cone blender. After sprayingof the solution has been completed, the material is warmed to evaporatethe solvent. The material is allowed to cool and then packaged.

EXAMPLE 14 Granule

[[2-[[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]phenyl]azo]phosphonicacid, dimethylester: 80%

wetting agent: 1%

crude ligninsulfonate salt (containing 5-20% of the natural sugars): 10%

attapulgite clay: 9%

The ingredients are blended and milled to pass through a 100 meshscreen. This material is then added to a fluid bed granulator, the airflow is adjusted to gently fluidize the material, and a fine spray ofwater is sprayed onto the fluidized material. The fluidization andspraying are continued until granules of the desired size range aremade. The spraying is stopped, but fluidization is continued, optionallywith heat, until the water content is reduced to the desired level,generally less than 1%. The material is then discharged, screened to thedesired size range, generally 14-100 mesh (1410-149 microns), andpackaged for use.

EXAMPLE 15 High Strength Concentrate

2-(dimethyl-1-triazeno)-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide:99%

silica aerogel: 0.5%

synthetic amorphous silica: 0.5%

The ingredients are blended and ground in a hammer-milll to produce amaterial essentially all passing a U.S.S. No. 50 screen (0.3 mmopening). The concentrate may be formulated further if necessary.

EXAMPLE 16 Wettable Powder

2-[4-(dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide:90%

dioctyl sodium sulfosuccinate: 0.1%

synthetic fine silica: 9.9%

The ingredients are blended and ground in a hammer-mill to produceparticles essentially all below 100 microns. The material is siftedthrough a U.S.S. No. 50 screen and then packaged.

EXAMPLE 17 Wettable Powder

[[2-[[(4-methoxy-6methylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]phenyl]azo]phosphonicacid, dimethylester: 40%

sodium ligninsulfonate: 20%

montmorillonite clay: 40%

The ingredients are thoroughly blended, coarsely hammer-milled and thenair-milled to produce particles essentially all below 10 microns insize. The material is reblended and then packaged.

EXAMPLE 18 Oil Suspension

2-(dimethyl-1-triazeno)-N-[(4-methoxy-6-methylpyrimidin-2yl)aminocarbonyl]benzenesulfonamide:35%

blend of polyalcohol carboxylic esters and oil soluble petroleumsulfonates: 6%

xylene: 59%

The ingredients are combined and ground together in a sand mill toproduce particles essentially all below 5 microns. The product can beused directly, extended with oils, or emulsified in water.

EXAMPLE 19 Dust

2-[4-(dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide:10%

attapulgite: 10%

Pyrophyllite: 80%

The active ingredient is blended with attapulgite and then passedthrough a hammer-mill to produce particles substantially all below 200microns. The ground concentrate is then blended with powderedpyrophyllite until homogeneous.

UTILITY

Test results indicate that the compounds of the present invention arehighly active preemergent or postemergent herbicides or plant growthregulants. Many of them have utility for broad-spectrum pre- and orpost-emergence weed control in areas where complete control of allvegetation is desired, such as around fuel storage tanks, ammunitiondepots, industrial storage areas, parking lots, drive-in theaters,around billboards, highway and railroad structures. Some of thecompounds have utility for selective weed control in crops such as wheatand cotton. Alternatively, the subject compounds are useful to modifyplant growth.

The rates of application for the compounds of the invention aredetermined by a number of factors, including their use as plant growthmodifiers or as herbicides, the crop species involved, the types ofweeds to be controlled, weather and climate, formulations selected, modeof application, amount of foliage present, etc. In general terms, thesubject compounds should be applied at levels of around 0.01 to 10 kg ofactive ingredient per hectare, the lower rates being suggested for useon lighter soils and/or those having a low organic matter content, forselective weed control or for situations where only short-termpersistence is required.

The compounds of the invention may be used in combination with any othercommercial herbicide; examples of which are those of the triazine,triazole, uracil, urea, amide, diphenylether, carbamate and bipyridyliumtypes.

The herbicidal properties of the subject compounds were discovered in anumber of greenhouse tests. The test procedures and results follow.##STR71##

TEST A

Seeds of crabgrass (Digitaria sp.), barnyardgrass (Echinochloacrusgalli), wild oats (Avena fatua), velvetleaf (Abutilon theophrasti),morningglory (Ipomoea spp.), cocklebur (Xanthium pensylvanicum),sicklepod (Cassia obtusifolia), cheatgrass (Bromus secalinus) bushbean,sorghum, corn, soybean, sugarbeet, cotton, rice, wheat and purplenutsedge (Cyperus rotundus) tubers were planted and treated preemergencewith the test chemicals dissolved in a non-phytotoxic solvent. At thesame time, these crop and weed species were treated with a soil/foliageapplication. At the time of treatment, the plants ranged in height from2 to 18 cm. Treated plants and controls were maintained in a greenhousefor sixteen days, after which all species were compared to controls andvisually rated for response to treatment. The ratings, summarized inTable A, are based on a numerical scale extending from 0=no injury, to10=complete kill. The accompanying descriptive symbols have thefollowing meanings:

C=chlorosis/necrosis;

B=burn;

D=defoliation;

E=emergence inhibition;

G=growth retardation;

H=formative effect;

U=unusual pigmentation;

X=axillary stimulation;

S=albinism; and

6Y=abscised buds or flowers.

                                      TABLE A                                     __________________________________________________________________________    TYPE                                                                              RATE                                                                              BUSH-                  SOY-     WILD-     BARNYARD                                                                              CRAB-               TEST                                                                              G/HA                                                                              BEAN COTTON                                                                              SORGHUM                                                                              CORN BEAN                                                                              WHEAT                                                                              OATS RICE GRASS   GRASS               __________________________________________________________________________            Compound 1                                                            Post                                                                              100 9C   8C    5U     5U   4C  7G   3C   4C   5C      2C                                     9G     9G   9G  9G   5G   9G   9H      6G                  Pre 100 --   --    1C     1C   5H  1C   1C   10E  1C      3C                                     9G     6G       5G   5G        9H      8G                          Compound 2                                                            Post                                                                              400 6C   3C    3C     5C   6C  0    0    --   2C      2C                          9G   3H    9G     9H   9G                 9H                                  6Y   8G                                                               Pre 400 --   -1C   1C     5H   5H  1C   1C   10E  2C      2C                               9G    9H              6G   5G        8H      8G                          Compound 3                                                            Post                                                                              400 --   4C    3C     3C   3C  5C   3C   5C   3C      4G                               9G    9G     9H   9G  9G   9G   9G   9H                          Post                                                                               50 --   2C    3C     3C   4C  0    0    5C   3C      2G                               9G    9H     9G   9G            9G   9H                          Pre 400 --   9G    3C     3C   8G  2C   2C   10E  2C      5G                                     9H     9G       9G   9G        9H                          Pre  50 --   2C    3C     2C   3C  8G   2C   3C   2C      0                                8G    8H     9G   7G       8G   8G   7G                                  Compound 4                                                            Post                                                                               50 --   10C   3C     3C   5C  3C   3C   6C   9H      6G                                     9H     9H   9H  6G   7G   9G                               Pre  50 --   9G    5C     3C   3C  8G   3C   4C   3C      4G                                     9H     9H   8H       8G   8G   9H                          __________________________________________________________________________                   TYPE                                                                              RATE                                                                              MORNING-                                                                             COCKLE-                                                                             SICKLE-                                                                             NUT- SUGAR-                                                                             VELVET-                                                                             CHEAT-                             TEST                                                                              G/HA                                                                              GLORY  BUR   POD   SEDGE                                                                              BEETS                                                                              LEAF  GRASS               __________________________________________________________________________                           Compound 1                                                            Post                                                                              100 10C    9C    6C    1C    --  --    --                                                      9G    8G                                                 Pre 100 8G     9H    9G    10E  --   --    --                                         Compound 2                                                            Post                                                                              400 8C     2C    2C    2C   --   --    --                                                7G    6G    8G                                                 Pre 400 9G     9H    9G    10E  --   --    --                                         Compound 3                                                            Post                                                                              400 3C     3C    5C    2C   4C   --    --                                         9G     9G    9G    9G   9G                                            Post                                                                               50 0      1C    3C    2C   5C   --    --                                                2G    8G    8G   9G                                            Pre 400 9G     9H    9G    9G   5C   --    --                                                                 9G                                            Pre  50 8G     9H    8G    7G   4C   --    --                                                                 9G                                                    Compound 4                                                            Post                                                                               50 3C     4C    --    6G   0C   9C    3C                                         7G     8H                          7G                                 Pre  50 7G     8H    --    3C   10C  10C   9H                                                            5G                                  __________________________________________________________________________

TEST B

Two 25 cm diameter plastic containers were lined with plastic bags andfilled with Woodstown sandy loam. A 25 cm diameter Lucite® plantingtemplate was used to slightly compress the soil within each containerand to provide indentations for the planting of nine crop or weedspecies. Seeds of the following species were placed in one container:mustard (Brassica nigra), cocklebur (Xantium pensylvanicum), velvetleaf(Abutilon theophrasti), sugar beets (Beta vulgaris), sicklepod (Cassiaobtusifolia), morningglory (Ipomoea spp.), purle nutsedge (Cyperusrotundus), pigweed (Amaranthus retroflexus), teaweed (Sida spinosa),cotton (Gossypium hirsutum), jimsonweed (Datura stramonium) and soybean(Glycine max.). The second pot was planted with seeds of the followingspecies: sorghum, (Sorghum bicolor), rice (Oryza sativa), giant foxtail(Setaria faberii), Dallisgrass (Paspalum diltatum), crabgrass (Digitariasanquinalis), bluegrass (Poa pratensis), johnsongrass (Sorghumhalepense), wild oats (Avena fatua), wheat (Triticum aestivum),cheatgrass (Bromus secalinus), barnyardgrass (Echinochloa crusgalli),and corn (Zea mays). Both containers were then topped with anapproximately 1 cm layer of soil to cover the seeds. These twocontainers were then sprayed preemergence with the test compoundsindicated in Table B. Following treatment, the plants were placed underan automatic overhead water device, where they received approximately 1cm of simulated rainfall in a period of 150 minutes.

Approximately twenty-eight days after treatment, the plants werevisually rated for response to the chemical treatments utilizing therating system as described for Test A. The resuls are presented in TableB.

                                      TABLE B                                     __________________________________________________________________________            BARN-                    JOHN-      GIANT                             RATE    YARD      WILD-                                                                              CRAB-                                                                              SOR- SON- DALLIS-                                                                             FOX- BLUE-                                                                              CHEAT-                  G/HA                                                                              RICE                                                                              GRASS                                                                              WHEAT                                                                              OATS GRASS                                                                              GHUM GRASS                                                                              GRASS TAIL GRASS                                                                              GRASS                                                                              CORN               __________________________________________________________________________    Compound 1                                                                    120 8E  7G   0    7G   0    8G   3H   7G    6G   7G   7G   2C                     9G  4C        3C        5H   6G         3C   5C   3C                      31.2                                                                              7G  4G   0    6G   0    5G   0    5G    0    7G   5G   0                                              3H                   3C                           Compound 2                                                                    250 8G  4G   3G   5G   0    7G   4G   0     0    3G   5G   2G                     3H                      5H                             2H                 62.5                                                                              --  0    --   0    0    0    3G   0     0    0    0    0                  __________________________________________________________________________                                MORN-           VEL-                              RATE                                                                              MUS-                                                                              COCKLE-                                                                             PIG- NUT- COT-                                                                              ING- SICKLE-                                                                             TEA- VET JIMSON-                                                                             SOY-                                                                              SUGAR-              G/HA                                                                              TARD                                                                              BUR   WEED SEDGE                                                                              TON GLORY                                                                              POD   WEED LEAF                                                                              WEED  BEAN                                                                              BEETS               __________________________________________________________________________    Compound 1                                                                    120 9G  5G    8G   6G   3H  7G   8G    5G   8G  5G    6G  8G                      9C        9C   3C   7G       9C         7C  3H    3H  8C                  31.2                                                                              8G  6G    8G   3G   2G  0    5G    0    6G  0     0   4G                      3C        8C                            5H                                Compound 2                                                                    250 8G  0     8G   0    0   3G   7G    5G   5G  0     3G  6G                      5C        9C                            5H            4C                  62.5                                                                              8G  0     7G   0    0   3G   0     0    3G  0     4G  4G                  __________________________________________________________________________

TEST C

In Test C, plastic pots filled with Fallsington sandy loam were plantedto soybeans, cotton, corn, rice, wheat, sorghum, velvetleaf (Abutilontheophrasti), sesbania (Sesbania exaltata), Sicklepod (Cassiaobtusifolia), morningglory (Ipomoea hederacea), jimsonweed (Daturastramonium), cocklebur (Xanthium pensylvanicum), crabgrass (Digitariasp.), nutsedge (Cyperus rotundus), barnyardgrass (Echinochloacrusgalli), giant foxtail (Setaria faberii) and wild oats (Avena fatua).Eighteen days after planting, the young plants and the soil around themwere sprayed overall with the test chemicals dissolved in anon-phytotoxic solvent. Fourteen days after treatment, all species werecompared to untreated controls and visually rated for response totreatment utilizing the rating system previously described for Test A.The ratings for the compound tested by this procedure are presented inTable C.

                                      TABLE C                                     __________________________________________________________________________    RATE                                                                              SOY-                   VELVET-                                                                             SES- SICKLE-                                                                             MORNING-                                                                             JIMSON-                                                                             COCKLE-              G/HA                                                                              BEAN                                                                              CORN                                                                              COTTON                                                                              RICE                                                                              WHEAT                                                                              LEAF  BANIA                                                                              POD   GLORY  WEED  BUR                  __________________________________________________________________________    Compound 2                                                                     62 7G  3G  7G    0   0    7G    7G   8G    9G     6G    2C                       3C  4H  3C             4C    3C   3C    4C     3C                         250 10G 6G  8G    4G  0    10G   10G  10G   9G     6G    6G                       4C  3H  5C    3C       8C    5C   6C    4C           3C                   __________________________________________________________________________                           RATE                                                                              CRAB-                                                                              BARNYARD-                                                                             GIANT-                                                                              WILD-       NUT-                                       G/HA                                                                              GRASS                                                                              GRASS   FOXTAIL                                                                             OATS SORGHUM                                                                              SEDGE               __________________________________________________________________________                               Compound 2                                                                 62 2G   3G      3G    2G   4G     1G                                         250 5G   7G      5G    6G   7G     1G                  __________________________________________________________________________

TEST D Postemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled withSassafras sandy loam soil. One pan was planted with blackgrass(Alopecurus myosuroides), sugarbeets, nutsedge (Cyperus rotundus)tubers,crabgrass (Digitaria sanguinalis), sicklepod (Cassia obtusifolia),teaweed (Sida spinosa), jimsonweed (Datura stramonium), velvetleaf(Abutilon theophrasti), and giant foxtail (Setaria faberii). The otherpan was planted with wheat, cotton, rice, corn, sugarbeet, soybean, wildoats (Avena fatua), cocklebur (Xanthium pensylvanicum), morningglory(Ipomoea hederacea), johnsongrass (Sorghum halepense) and barnyardgrass(Echinochloa crusgalli). The plants were grown for approximatelyfourteen days, then sprayed postemergence with the chemicals dissolvedin a non-phytoxic solvent.

Preemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled withSassafras sandy loam soil. One pan was planted with blackgrass,sugarbeets, nutsedge, crabgrass, sicklepod, teaweed, jimsonweed,velvetleaf, and giant foxtail. The other pan was planted with wheat,cotton, rice, corn, sugarbeet, soybean, wild oats, cocklebur,morningglory, johnsongrass and barnyardgrass. The two pans were sprayedpre-emergence with the chemicals dissolved in a non-phytoxic solvent.

Treated plants and controls were maintained in the greenhouse for 28days, then all treated plants were compared to controls and visuallyrated for plant response utilizing the rating system previouslydescribed for Test A.

                                      TABLE D                                     __________________________________________________________________________    TYPE                                                                              RATE              SOY-       SUGAR-                                                                             CRAB-                                                                              JOHNSON-                                                                             BLACK-                                                                             BARNYARD-              TEST                                                                              G/HA                                                                              CORN WHEAT                                                                              RICE                                                                              BEAN COTTON                                                                              BEET GRASS                                                                              GRASS  GRASS                                                                              GRASS                  __________________________________________________________________________    POST                                                                              250 10G  0    10G 10G  10G   10C  3G   4G     8G   9G                          62 10G  0    10G 9G   9G    10C  0    0      5G   7G                          16 6G   0    6G  9G   4G    7G   0    0      0    3G                          4  2G   0    0   4G   0     3G   0    0      0    0                      PRE 250 9G   0    10E 8G   8G    10G  4G   6G     6G   9G                          62 9G   0    9G  6G   6G    7G   3G   0      3G   4G                          16 3G   0    8G  3G   3G    4G   0    0      0    2G                          4  0    0    3G  0    0     0    0    0      0    0                      __________________________________________________________________________    TYPE                                                                              RATE                                                                              NUT-  GIANT-                                                                              WILD- COCKLE-                                                                             MORNING-                                                                             TEA-  SICKLE-                                                                             JIMSON-                                                                             VELVET-              TEST                                                                              G/HA                                                                              SEDGE FOXTAIL                                                                             OATS  BUR   GLORY  WEED  POD   WEED  LEAF                 __________________________________________________________________________    POST                                                                              250 10C   5G    3G     10G  7G     8G    10G   8G    10C                       62 4G    3G    0     5G    5G     5G    3G    5G    10G                       16 0     0     0     0     0      3G    0     0     7G                        4  0     0     0     0     0      0     0     0     2G                   PRE 250 0     3G    3G    9G    0      8G    10E   9G    10G                       62 0     0     0     9G    0      4G    10E   4G    6G                        16 0     0     0     3G    0      2G    4G    2G    4G                        4  0     0     0     0     0      0     0     0     3G                   __________________________________________________________________________

What is claimed is:
 1. A compound of Formulae I or II ##STR72## whereinR is H or CH₃ ;R₁ is NR₄ R₅, N(CH₃)OR₆, NHCN, NRA, P(W)R₄ (W₁ R₅),P(W)(W₁ R₄)(W₂ R₅), P⁺ (C₆ H₅)₃, P⁺ R₆ R₇ R₈, SR₉, SO₂ R₉,C(R₁₀)(R₁₁)NO₂, CH(CN)₂ or Q; Q is ##STR73## R₂ is H, F, Cl, Br, OCH₃,OC₂ H₅, OCF₂ H, SCH₃, N(CH₃)₂, NO₂, CH₃ or CF₃ ; R₃ is H, F, Cl, Br, C₁-C₄ alkyl, CO₂ R₁₅, NO₂, CF₃, C₁ -C₄ alkoxy, C₁ -C₄ alkylthio, SO₂ NR₁₆R₁₇, C₁ -C₄ alkylsulfonyl, C₁ -C₄ haloalkoxy, C₁ -C₄ alkylsulfonyloxy,C₂ -C₅ alkoxyalkyl or C₃ -C₄ alkenyloxy; R₄ and R₅ are independently C₁-C₄ alkyl, C₂ -C₄ alkyl substituted by 1 atom of Br or 1-3 atoms of F orCl, C₃ -C₅ alkenyl, C₃ -C₅ cycloalkyl, OH, OCH₃, CH₂ OH, CH₂ OR₆, or CH₂CH₂ OR₆ ; or R₄ and R₅ may be taken together as --(CH₂)₄ --, --(CH₂)₅ --or --(CH₂)₂ O(CH₂)₂ --; R₆ is C₁ -C₄ alkyl; R₇ and R₈ are independentlyC₁ -C₄ alkyl; R₉ is C₁ -C₄ alkyl, phenyl or phenyl substituted with 1-3atoms of F, Cl or 1Br; R₁₀ and R₁₁ are independently H, C₁ -C₄ alkyl,phenyl or phenyl substituted with 1 atom of Br or 1-3 atoms of F or Cl;R₁₂ is C₁ -C₄ alkyl, C₁ -C₄ alkoxy or NHR₉ ; R₁₃ and R₁₄ areindependently H, C₁ -C₃ alkyl, OR₆, SR₆, NHC(O)R₆, F, Cl, Br or CO₂ R₆ ;R₁₅ is C₁ -C₄ alkyl, C₃ -C₄ alkenyl, CH₂ CH₂ Cl or CH₂ CH₂ OCH₃ ; R₁₆and R₁₇ are independently C₁ -C₂ alkyl; W is O or S; W₁ and W₂ areindependently O, S or NH; A is ##STR74## X is CH₃, OCH₃, OCH₂ CH₃, Cl,F, Br, I, OCF₂ H, CH₂ F, OCH₂ CH₂ F, OCH₂ CHF₂, OCH₂ CF₃ or CF₃ ; Y isH, C₁ -C₃ alkyl,, OCH₃, OC₂ H₅, CH₂ OCH₃, NHCH₃, N(OCH₃)CH₃, N(CH₃)₂,CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, CH₂ OCH₂ CH₃, OCH₂ CH₂ OCH₃,##STR75## OCF₂ H, SCF₂ H or cyclopropyl; m is 2 or 3; L₁ and L₂ areindependently O or S; R₁₈ is H or CH₃ ; Z is CH; Y₁ is O or CH₂ ; X₁ isCH₃, OCH₃, OC₂ H₅ or OCF₂ H; and Y₂ is H or CH₃ ;provided that (a) whenX is Cl, F, Br or I, then Y is OCH₃, OC₂ H₅, N(OCH₃)CH₃, NHCH₃, N(CH₃)₂or OCF₂ H; and (b) when Q is Q-11 or Q-12, then R₁₃ is other than H;andtheir agriculturally suitable salts.
 2. A compound of claim 1 wherein Ris hydrogen and A is ##STR76##
 3. A compound of claim 2 wherein X isCH₃, OCH₃ or Cl and Y is CH₃, OCH₃, OC₂ H₅ or CH₂ OCH₃.
 4. A compound ofclaim 3 wherein R₂ is H, Cl, CH₃ or OCH₃ and R₃ is Cl, C₁ -C₃ alkyl, C₁-C₃ alkoxy, NO₂, CO₂ (C₁ -C₃ alkyl), SO₂ N(CH₃)₂, OSO₂ CH₃, OSO₂ C₂ H₅,SO₂ CH₃, SO₂ C₂ H₅ or allyloxy.
 5. The compound of claim 1 that is2-[4-(dimethylamino)phenylazo]-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide.6. The compound of claim 1 that is[[2-[[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]phenyl]azo]phosphonicacid, dimethylester.
 7. The compound of claim 1 that is2-(dimethyl-1-triazeno)-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide.8. A composition for the control of undesirable vegetation consistingessentially of a compound of claim 1 and at least one of (a) a surfaceactive agent, and (b) a solid or liquid diluent.
 9. A composition forthe control of undesirable vegetation consisting essentially of acompound of claim 2 and at least one of (a) a surface active agent, and(b) a solid or liquid diluent.
 10. A composition for the control ofundesirable vegetation consisting essentially of a compound of claim 3and at least one of (a) a surface active agent, and (b) a solid orliquid diluent.
 11. A composition for the control of undesirablevegetation consisting essentially of a compound of claim 4 and at leastone of (a) a surface active agent, and (b) a solid or liquid diluent.12. A composition for the control of undesirable vegetation consistingessentially of a compound of claim 5 and at least one of (a) a surfaceactive agent, and (b) a solid or liquid diluent.
 13. A composition forthe control of undesirable vegetation consisting essentially of acompound of claim 6 and at least one of (a) a surface active agent, and(b) a solid or liquid diluent.
 14. A composition for the control ofundesirable vegetation consisting essentially of a compound of claim 7and at least one of (a) a surface active agent, and (b) a solid orliquid diluent.
 15. A method for the control of undesirable vegetationcomprising applying to the locus of such vegetation an herbicidallyeffective amount of a compound of claim
 1. 16. A method for the controlof undesirable vegetation comprising applying to the locus of suchvegetation an herbicidally effective amount of a compound of claim 2.17. A method for the control of undesirable vegetation comprisingapplying to the locus of such vegetation an herbicidally effectiveamount of a compound of claim
 3. 18. A method for the control ofundesirable vegetation comprising applying to the locus of suchvegetation an herbicidally effective amount of a compound of claim 4.19. A method for the control of undesirable vegetation comprisingapplying to the locus of such vegetation an herbicidally effectiveamount of a compound of claim
 5. 20. A method for the control ofundesirable vegetation comprising applying to the locus of suchvegetation an herbicidally effective amount of a compound of claim 6.21. A method for the control of undesirable vegetation comprisingapplying to the locus of such vegetation an herbicidally effectiveamount of a compound of claim 7.